{"id":"W2056041629","doi":"10.1039/c4cc04545a","title":"Influence of redox non-innocent phenylenediamido ligands on chromium imido hydrogen-atom abstraction reactivity","year":2014,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia, Okanagan Campus; University of British Columbia","funders":"","keywords":"Reactivity (psychology); Chromium; Redox; Hydrogen atom abstraction; Chemistry; Hydrogen; Atom (system on chip); Hydrogen atom; Inorganic chemistry; Organic chemistry; Group (periodic table)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000246517,0.0001986325,0.0002964141,0.00005809047,0.0001749524,0.00002321949,0.0009115053,0.0002115729,0.00006458331],"category_scores_gemma":[0.0003955748,0.0002001124,0.0001591022,0.000200245,0.0002889952,0.0001621052,0.0002166331,0.0004938646,0.00008388748],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001561492,"about_ca_system_score_gemma":0.0000603157,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000939664,"about_ca_topic_score_gemma":0.000005884673,"domain_scores_codex":[0.998713,0.0000214675,0.0004707294,0.0002988285,0.0002663881,0.0002295545],"domain_scores_gemma":[0.9958982,0.0007954235,0.000321686,0.002701005,0.000148439,0.0001352345],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002070952,0.0005014561,0.0003321898,0.00003969867,0.0000367105,1.391828e-7,0.00008032702,0.00006761798,0.9945866,0.0009042962,0.0001812453,0.003249042],"study_design_scores_gemma":[0.0002628879,0.00001276576,0.001961786,0.0001148991,0.00005499921,0.000006693137,0.00006214855,0.0007285306,0.9779227,0.0004810441,0.01820138,0.0001901274],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9504169,0.00005504724,0.00003697734,0.00098181,0.00002346236,0.00006902967,0.00002886166,0.00008804684,0.04829992],"genre_scores_gemma":[0.9988924,0.0002050435,0.0003782258,0.00008243939,0.0001027541,0.00007410107,0.0001283342,0.00002873082,0.0001079431],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04847559,"threshold_uncertainty_score":0.8160345,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01445394582535821,"score_gpt":0.2576195060696472,"score_spread":0.243165560244289,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}