{"id":"W2056317070","doi":"10.1021/ic2013667","title":"Singlet and Triplet Energy Transfers in Tetra-(<i>meso</i>-truxene)zinc(II)- and Tetra-(<i>meso</i>-tritruxene)zinc(II) Porphyrin and Porphyrin-Free Base Dendrimers","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Porphyrin; Photochemistry; Chromophore; Free base; Phosphorescence; Acceptor; Singlet state; Dendrimer; Fluorescence; Zinc; Tetra; Polymer chemistry; Excited state; Physical chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007814873,0.0001670214,0.000128262,0.0001355285,0.0001343671,0.0001709504,0.0001397652,0.0001811545,0.0006560339],"category_scores_gemma":[0.0001565105,0.000109054,0.00009711707,0.0001101651,0.0001283745,0.0002174913,0.0001306361,0.0001658478,0.000154689],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005100357,"about_ca_system_score_gemma":0.0001721411,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007646843,"about_ca_topic_score_gemma":0.0008618187,"domain_scores_codex":[0.9999442,0.000006217239,0.000002887637,0.00001273973,0.00001606986,0.00001790819],"domain_scores_gemma":[0.9999379,0.00001456848,0.00001892446,0.000004653254,0.00001134743,0.00001263436],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004952392,0.00000612855,0.0001127878,0.00001512226,0.000001833017,0.00002337489,0.00001839896,0.0002578732,0.9987656,0.00007843916,0.00001028139,0.0006607398],"study_design_scores_gemma":[0.000005844254,0.00008367433,0.001230534,0.000001620188,0.000003393341,0.00004773976,0.0000122037,0.001098929,0.9972089,0.00002459774,0.0002792969,0.000003247489],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9990987,0.0001413702,0.0003888003,0.000007665919,0.000001687574,0.000003802451,0.00002203053,0.00001124512,0.00032474],"genre_scores_gemma":[0.9980925,0.0001360553,0.0005562576,0.000004664032,7.926847e-7,0.000008420075,0.00004192652,0.000005711707,0.001153698],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007646843,"threshold_uncertainty_score":0.003700614,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01348243598840332,"score_gpt":0.1905845268084317,"score_spread":0.1771020908200284,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}