{"id":"W2056317070","doi":"10.1021/ic2013667","title":"Singlet and Triplet Energy Transfers in Tetra-(<i>meso</i>-truxene)zinc(II)- and Tetra-(<i>meso</i>-tritruxene)zinc(II) Porphyrin and Porphyrin-Free Base Dendrimers","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Porphyrin; Photochemistry; Chromophore; Free base; Phosphorescence; Acceptor; Singlet state; Dendrimer; Fluorescence; Zinc; Tetra; Polymer chemistry; Excited state; Physical chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006690248,0.001023983,0.001035283,0.0001673037,0.0004982746,0.0001694223,0.0009765581,0.0006708401,0.001839679],"category_scores_gemma":[0.0002580462,0.001091605,0.0001824837,0.0005882591,0.0009442928,0.0004750511,0.0008419266,0.0006809469,0.00001477503],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001893897,"about_ca_system_score_gemma":0.0003254589,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008631605,"about_ca_topic_score_gemma":0.00008676247,"domain_scores_codex":[0.9951068,0.0001017725,0.001104196,0.001772995,0.0006259675,0.001288275],"domain_scores_gemma":[0.9972449,0.000190074,0.0003024409,0.001270353,0.0001112299,0.0008810076],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002343606,0.0003810266,0.005090945,0.000405199,0.00005766673,0.0003566095,0.001011696,8.875755e-7,0.9903529,0.0001092388,0.001307947,0.0006914829],"study_design_scores_gemma":[0.00432342,0.0002193364,0.002884456,0.0001922149,0.0001313486,0.001372145,0.0004913613,0.00003575546,0.9857556,0.0008447099,0.002478484,0.001271143],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9855347,0.002986066,0.00002633843,0.0002891431,0.0002424595,0.0002478226,0.0004679976,0.0002325669,0.009972896],"genre_scores_gemma":[0.9961007,0.0006462588,0.001111966,0.0004220343,0.0002390316,0.00004587167,0.00009164422,0.0001376735,0.001204796],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01056601,"threshold_uncertainty_score":0.9991534,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01348243598840332,"score_gpt":0.1905845268084317,"score_spread":0.1771020908200284,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}