{"id":"W2056557733","doi":"10.1021/np060454v","title":"Isolation and Structure Elucidation by LC-MS-SPE/NMR:  PR Toxin- and Cuspidatol-Related Eremophilane Sesquiterpenes from <i>Penicillium </i><i>roqueforti</i>","year":2006,"lang":"en","type":"article","venue":"Journal of Natural Products","topic":"Toxin Mechanisms and Immunotoxins","field":"Immunology and Microbiology","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University; Agriculture and Agri-Food Canada","funders":"","keywords":"Penicillium roqueforti; Sesquiterpene; Stereochemistry; Penicillium; Chemistry; Two-dimensional nuclear magnetic resonance spectroscopy; Toxin; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009528761,0.0006142685,0.0002437989,0.0003697844,0.0002007544,0.0002063023,0.0001649492,0.0002680746,0.001108451],"category_scores_gemma":[0.0002039939,0.000107635,0.0001951029,0.0002824485,0.0002338387,0.0002635869,0.000133455,0.0004700813,0.0004978392],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002510024,"about_ca_system_score_gemma":0.0003555483,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009166621,"about_ca_topic_score_gemma":0.001749956,"domain_scores_codex":[0.999946,0.000005877562,0.000004249147,0.00001304339,0.00001752697,0.00001325842],"domain_scores_gemma":[0.9999126,0.00001883926,0.00002149763,0.000008932398,0.00002156167,0.00001652741],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004669097,0.000007760276,0.0001172128,0.00003359373,0.000002902379,0.0001126678,0.0000131794,0.00004602534,0.9970968,0.00002772248,0.00001233714,0.002483198],"study_design_scores_gemma":[0.00002842663,0.000245511,0.006815605,0.000009691524,0.00002171126,0.00075552,0.00004360277,0.0003849436,0.9892392,0.0000951418,0.002348909,0.0000116804],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9827141,0.002736226,0.01051294,0.0001951462,0.00002568839,0.0001021419,0.001448566,0.00007909623,0.00218611],"genre_scores_gemma":[0.9573032,0.003747838,0.02861333,0.0002681747,0.00003204139,0.0001136199,0.005209931,0.00004336085,0.004668405],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001108451,"threshold_uncertainty_score":0.003708065,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003307770177799538,"score_gpt":0.1907744892277623,"score_spread":0.1874667190499628,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}