{"id":"W2056847123","doi":"10.1021/ja049761i","title":"Regio- and Enantiocontrol in the Room-Temperature Hydroboration of Vinyl Arenes with Pinacol Borane","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":200,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Hydroboration; Borane; Pinacol; Catechol; Organic chemistry; Castanospermine; Selectivity; Methyl vinyl ketone; Cyclohexanes; Catalysis; Medicinal chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001746349,0.0001562934,0.0003541238,0.000008869631,0.00005843466,0.0000319196,0.0004002639,0.00009194195,0.00001498595],"category_scores_gemma":[0.00007199042,0.00007987586,0.000198364,0.0003113032,0.0003972719,0.00008390586,0.00004056518,0.0005576393,1.893388e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000114712,"about_ca_system_score_gemma":0.000146593,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003699507,"about_ca_topic_score_gemma":0.000004941777,"domain_scores_codex":[0.9989632,0.00002282933,0.000349876,0.0001370491,0.0003541046,0.000172934],"domain_scores_gemma":[0.9988574,0.00008317793,0.0006495589,0.0002510468,0.0001001287,0.00005867986],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009686162,0.0001263304,0.004081481,0.00006364818,0.00005968965,0.000004650153,0.0007693333,0.00005945237,0.994103,0.000008860774,0.0004779099,0.0001487986],"study_design_scores_gemma":[0.001385529,0.000051667,0.001688649,0.000149805,0.00006409953,0.0001628557,0.002143858,0.000008196115,0.9939792,0.00009814923,0.0001606432,0.0001074168],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927726,0.0003404636,0.00001109464,0.006730583,0.00001603838,0.00005435646,0.000005895649,0.000006298714,0.0000626303],"genre_scores_gemma":[0.9985281,0.0001876993,0.0003642925,0.0006854169,0.0002005966,0.000002918315,0.000001417963,0.00001489499,0.0000146765],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006045166,"threshold_uncertainty_score":0.3257243,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003791032243965909,"score_gpt":0.2116191072638106,"score_spread":0.2078280750198447,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}