{"id":"W2056884784","doi":"10.1002/ejoc.200600916","title":"Can Four‐Membered Heterophosphete Structures Exist? The Contribution of Phosphorus d Orbitals to Antiaromaticity","year":2007,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Hungarian Scientific Research Fund","keywords":"Antiaromaticity; Chemistry; Heteroatom; Ring (chemistry); Atomic orbital; Phosphorus; Aromaticity; Atom (system on chip); Computational chemistry; Molecular orbital; Stereochemistry; Electron; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002571471,0.0002347626,0.0003653853,0.0004551632,0.00046572,0.0008549115,0.0004692027,0.0008451057,0.003814979],"category_scores_gemma":[0.0004540016,0.0002123244,0.0001591903,0.0002523339,0.0007382452,0.0008907256,0.0005638362,0.0003410773,0.0003477974],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001620829,"about_ca_system_score_gemma":0.000143156,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001261509,"about_ca_topic_score_gemma":0.0001825223,"domain_scores_codex":[0.9999279,0.00001111451,0.000004336919,0.00001653421,0.00001714913,0.00002306992],"domain_scores_gemma":[0.9998085,0.00007998878,0.00004168838,0.00003308925,0.00001290905,0.00002388562],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00171394,0.0001901955,0.01442243,0.0009039893,0.0001501269,0.002960754,0.0006267782,0.04876127,0.5833133,0.2959494,0.001509923,0.04949785],"study_design_scores_gemma":[0.0002683278,0.001669991,0.01663177,0.0001044648,0.0002021236,0.002933174,0.0009921991,0.2945254,0.2803792,0.3893745,0.01275335,0.0001655377],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9855532,0.0004090524,0.008182842,0.0002347689,0.00002829949,0.00001020627,0.00006499673,0.0001007465,0.005415897],"genre_scores_gemma":[0.998998,0.0001162276,0.0004985079,0.00002246383,0.000006789039,0.000007779946,0.00003125398,0.000006870075,0.0003121629],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003814979,"threshold_uncertainty_score":0.01276231,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0106377939202869,"score_gpt":0.2152056514674542,"score_spread":0.2045678575471672,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}