{"id":"W2057112488","doi":"10.1021/jp901235w","title":"A <sup>47/49</sup>Ti Solid-State NMR Study of Layered Titanium Phosphates at Ultrahigh Magnetic Field","year":2009,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Western University","funders":"","keywords":"Coordination sphere; Solid-state nuclear magnetic resonance; NMR spectra database; Octahedron; Quadrupole; Electric field gradient; Chemistry; Titanium; Spectral line; Crystallography; Intercalation (chemistry); Materials science; Nuclear magnetic resonance; Inorganic chemistry; Crystal structure; Atomic physics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007234432,0.0001078272,0.0000810615,0.0001128543,0.000192368,0.0001375077,0.0001899236,0.0001725069,0.001053761],"category_scores_gemma":[0.0001135861,0.00007676151,0.00006678381,0.0001037032,0.0002065036,0.0002242337,0.0001151296,0.0001908192,0.000185315],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001134027,"about_ca_system_score_gemma":0.0000734019,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006749504,"about_ca_topic_score_gemma":0.0006639577,"domain_scores_codex":[0.9999672,0.000003445045,0.000001550297,0.000005783776,0.00001540173,0.000006666793],"domain_scores_gemma":[0.9999428,0.00001200993,0.00001388192,0.000004249117,0.00001801001,0.000009167919],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004359154,0.00000570584,0.0003816691,0.00003031642,0.000003512585,0.000068649,0.00003650559,0.0002323852,0.9981897,0.00008472802,0.00006912899,0.0008540488],"study_design_scores_gemma":[0.000006710912,0.0001075054,0.006567419,0.000003931871,0.000008979456,0.0001641313,0.00010756,0.00449502,0.9874423,0.0000695183,0.00101928,0.000007641951],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971356,0.000151646,0.001379735,0.00005135144,0.000006910866,0.000003347615,0.00008641488,0.00002913468,0.001155892],"genre_scores_gemma":[0.9972377,0.0001463449,0.001720144,0.0000226572,0.000006228123,0.000004841917,0.000157855,0.000009664446,0.0006946328],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001053761,"threshold_uncertainty_score":0.003525138,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008419634456137826,"score_gpt":0.2754282533213464,"score_spread":0.2670086188652085,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}