{"id":"W2057145680","doi":"10.1139/v01-024","title":"Réaction compétitive de la substitution homolytique intramoléculaire : décomposition de peroxydes allyliques dans le thioglycolate de méthyle","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Homolysis; Allylic rearrangement; Intramolecular force; Epoxide; Peroxide; Medicinal chemistry; Hydrogen peroxide; Adduct; Stereochemistry; Radical; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007676584,0.0005242619,0.0004420676,0.0001745179,0.0003043938,0.000494843,0.0003938836,0.0004099071,0.003672722],"category_scores_gemma":[0.00102484,0.0002555104,0.0002523529,0.000143162,0.0003848601,0.0007767563,0.0003720811,0.0007977347,0.0005799198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005099278,"about_ca_system_score_gemma":0.0003948164,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001298096,"about_ca_topic_score_gemma":0.001499748,"domain_scores_codex":[0.9995585,0.0001049173,0.00001362803,0.00009077867,0.0001089914,0.0001231459],"domain_scores_gemma":[0.9993774,0.0003180946,0.00008933363,0.00006394623,0.00009138175,0.00005985804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000425718,0.00006332473,0.0003751103,0.0001028875,0.00003745362,0.0001261979,0.00006263802,0.0002882036,0.9925764,0.001052562,0.00006067097,0.004828898],"study_design_scores_gemma":[0.00003889178,0.0004449853,0.0008585876,0.000005022654,0.00002930447,0.0001496226,0.00002456046,0.001390363,0.9960343,0.0001380448,0.0008772594,0.000009038268],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903211,0.001153201,0.004719121,0.00009453989,0.00003471205,0.00006320271,0.00004232422,0.00003662849,0.003535184],"genre_scores_gemma":[0.9951885,0.0004510281,0.001422782,0.00002056299,0.00001587934,0.00002930632,0.00004324441,0.0000177645,0.002810947],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003672722,"threshold_uncertainty_score":0.01228648,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005179668577237925,"score_gpt":0.2083577311328865,"score_spread":0.2031780625556486,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}