{"id":"W2057183351","doi":"10.1016/j.eurpolymj.2006.12.037","title":"The effect of thiolation on the mechanical and protein adsorption properties of polyurethanes","year":2007,"lang":"en","type":"article","venue":"European Polymer Journal","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Polybutadiene; Polyurethane; Polymer; Materials science; Ultimate tensile strength; Adsorption; Polymer chemistry; Grafting; Carboxylate; Degree of unsaturation; Side chain; Sulfonate; Elastomer; Protein adsorption; Chemical engineering; Composite material; Chemistry; Copolymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.005257789,0.00013079,0.0001638436,0.00004559242,0.0003583706,0.0000925967,0.0002759809,0.00003188895,0.0000453712],"category_scores_gemma":[0.0002101417,0.00005064185,0.00007091612,0.00007046985,0.0002584028,0.000100898,0.00006005665,0.0001978671,0.00001383357],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000008242259,"about_ca_system_score_gemma":0.00001675627,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002383305,"about_ca_topic_score_gemma":0.000003754891,"domain_scores_codex":[0.9977399,0.001155111,0.0004280671,0.0001176578,0.0003483834,0.0002108703],"domain_scores_gemma":[0.9991048,0.0002563438,0.0003353291,0.000204172,0.00004667373,0.0000526871],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006149301,0.00001135382,0.00006562666,0.00001869826,0.00001339688,0.000001377725,0.0003195069,1.784347e-7,0.9696193,0.000865333,0.00003652868,0.02843373],"study_design_scores_gemma":[0.0001851455,0.0005301241,0.0006054631,0.000216555,0.00002074517,0.0000471849,0.0001232243,0.00002251646,0.9979402,0.00003090178,0.0002093214,0.00006865703],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9810393,0.01646435,0.0001248534,0.0008841451,0.000200468,0.0001533567,0.000001790904,0.00001191172,0.001119795],"genre_scores_gemma":[0.9993886,0.00006735048,0.00002314466,0.00004255608,0.0001603615,0.000001903702,1.008453e-7,0.00001683803,0.0002991218],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02836507,"threshold_uncertainty_score":0.2756333,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01776678883394049,"score_gpt":0.2105787737768131,"score_spread":0.1928119849428726,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}