{"id":"W2057210162","doi":"10.1039/b919233f","title":"Reductive dearomatization of a substituted benzene triggered by a strong oxidant","year":2009,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Ontario Ministry of Research and Innovation; Natural Sciences and Engineering Research Council of Canada","keywords":"Benzene; Chemistry; Reactivity (psychology); Platinum; Medicinal chemistry; Scavenger; Reductive elimination; Benzene derivatives; Stereochemistry; Radical; Organic chemistry; Catalysis; Chemical synthesis; In vitro","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007190976,0.0001860128,0.0001575501,0.00005574813,0.00008087049,0.0001217727,0.000224402,0.0002271185,0.0009878071],"category_scores_gemma":[0.0001100689,0.0000835443,0.00009904896,0.00006433942,0.00009305964,0.0001518797,0.0001529432,0.0002419494,0.0002201701],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002038102,"about_ca_system_score_gemma":0.00007942132,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003494524,"about_ca_topic_score_gemma":0.0008439694,"domain_scores_codex":[0.9999176,0.0000121921,0.000004088985,0.00002114451,0.00001905746,0.00002594186],"domain_scores_gemma":[0.999956,0.000005741669,0.00001648852,0.000004948948,0.000007302251,0.000009624935],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005255582,0.000006847739,0.00003726254,0.00002314776,0.000002604687,0.00002417896,0.00001490204,0.00004819643,0.9987992,0.0001125867,0.00003092858,0.0008475808],"study_design_scores_gemma":[0.00000571229,0.00007958084,0.0002261435,8.125342e-7,0.00000246794,0.00003278893,0.000003830261,0.0002770636,0.9983466,0.00001175997,0.001011635,0.000001508856],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912015,0.000860937,0.005075575,0.0001070641,0.00002098262,0.00002029538,0.0001552186,0.00009546573,0.002462775],"genre_scores_gemma":[0.9965851,0.0002351564,0.001560244,0.00002800323,0.000003148517,0.000006611427,0.0000848659,0.000008840809,0.001487994],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009878071,"threshold_uncertainty_score":0.003304541,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01113483935000691,"score_gpt":0.2401294995488532,"score_spread":0.2289946601988463,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}