{"id":"W2057221642","doi":"10.1021/jo1016713","title":"Synthesis of Substituted Indole from 2-Aminobenzaldehyde through [1,2]-Aryl Shift","year":2010,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Chemistry; Indole test; Anthranilic acid; Aryl; Functional group; Combinatorial chemistry; Ethyl diazoacetate; Organic chemistry; Stereochemistry; Catalysis; Cyclopropanation","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001085013,0.000409369,0.0002077123,0.0002057365,0.0002030034,0.000169332,0.0003670099,0.0001978678,0.00152024],"category_scores_gemma":[0.00007429548,0.0001687359,0.0002290136,0.0001580554,0.000139247,0.0001907608,0.000202061,0.0004581124,0.001002919],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002176008,"about_ca_system_score_gemma":0.0003451642,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005825057,"about_ca_topic_score_gemma":0.002047537,"domain_scores_codex":[0.9999311,0.000007937978,0.000004406069,0.00001221202,0.00002062589,0.00002373436],"domain_scores_gemma":[0.9999652,0.000004082299,0.000008922922,0.000005512531,0.000007298182,0.000009026486],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002812995,0.00002788112,0.00006889162,0.00011088,0.000006232103,0.0002343445,0.00003828433,0.0001877137,0.9912338,0.001080647,0.0001904475,0.006792699],"study_design_scores_gemma":[0.00001349087,0.0001740424,0.000786737,0.00001082699,0.00001301152,0.0003192219,0.0000107942,0.0008925259,0.9844264,0.0001584667,0.0131799,0.00001448099],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8061941,0.01197039,0.1383184,0.0004799672,0.000417476,0.0002962855,0.0009942456,0.001500337,0.03982871],"genre_scores_gemma":[0.946031,0.004970625,0.03739743,0.00009406375,0.00003572662,0.00008761579,0.0005712885,0.00009071957,0.01072149],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00152024,"threshold_uncertainty_score":0.005085707,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008555488539771863,"score_gpt":0.2163312935410698,"score_spread":0.207775805001298,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}