{"id":"W2057396909","doi":"10.1002/pola.21011","title":"Kinetics and mechanisms in carbocationic polymerization: The quest for true rate constants","year":2005,"lang":"en","type":"article","venue":"Journal of Polymer Science Part A Polymer Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Lanxess (Canada); Western University; Queen's University","funders":"Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Polymerization; Reaction rate constant; Taft equation; Kinetics; Thermodynamics; Activation energy; Reaction mechanism; Kinetic energy; Cationic polymerization; Physical chemistry; Polymer chemistry; Stereochemistry; Polymer; Organic chemistry; Physics; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002203701,0.001014077,0.0007930268,0.0008466049,0.0002437775,0.001140851,0.001341127,0.0007867867,0.001561909],"category_scores_gemma":[0.004264485,0.0008407387,0.0006803728,0.0003188392,0.001113321,0.004377234,0.000413493,0.002667802,0.0005280023],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001202024,"about_ca_system_score_gemma":0.0004273934,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003524206,"about_ca_topic_score_gemma":0.0002104803,"domain_scores_codex":[0.9992419,0.000146817,0.00006115236,0.0002272643,0.0002282585,0.00009464358],"domain_scores_gemma":[0.9973511,0.001917026,0.0003464859,0.0001611548,0.0001845998,0.00003972571],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002619696,0.0003054973,0.002823554,0.005997225,0.0001596312,0.0004074344,0.0007896254,0.0311778,0.766223,0.1087966,0.0009034346,0.08215413],"study_design_scores_gemma":[0.00001986971,0.0004934142,0.002680175,0.0002760843,0.0001024031,0.0005678199,0.000214897,0.06345218,0.8707287,0.04463041,0.01665528,0.0001788081],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4384928,0.1700283,0.377893,0.002007872,0.0004983425,0.0002499551,0.000439101,0.0007738993,0.009616738],"genre_scores_gemma":[0.8856091,0.07693501,0.03290976,0.000208729,0.000194811,0.0002523341,0.0002172433,0.0001657955,0.003507307],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002203701,"threshold_uncertainty_score":0.01165444,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01149241450688706,"score_gpt":0.2582826083630815,"score_spread":0.2467901938561945,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}