{"id":"W2057396909","doi":"10.1002/pola.21011","title":"Kinetics and mechanisms in carbocationic polymerization: The quest for true rate constants","year":2005,"lang":"en","type":"article","venue":"Journal of Polymer Science Part A Polymer Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Lanxess (Canada); Western University; Queen's University","funders":"Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Polymerization; Reaction rate constant; Taft equation; Kinetics; Thermodynamics; Activation energy; Reaction mechanism; Kinetic energy; Cationic polymerization; Physical chemistry; Polymer chemistry; Stereochemistry; Polymer; Organic chemistry; Physics; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006554042,0.0002603525,0.000331184,0.00009454828,0.0002067916,0.0001610405,0.0006933342,0.0001515783,0.0003971501],"category_scores_gemma":[0.0003240649,0.0002075309,0.0001159449,0.0005367834,0.0006502097,0.0004050487,0.000103846,0.0003657615,0.000002944179],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002110499,"about_ca_system_score_gemma":0.0004812621,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001245867,"about_ca_topic_score_gemma":0.000005928185,"domain_scores_codex":[0.9976366,0.00001832037,0.0008290525,0.0003878704,0.0006042873,0.0005238612],"domain_scores_gemma":[0.9981757,0.0002603328,0.0006401002,0.0004023024,0.0002049482,0.0003165958],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005299949,0.00009580435,0.00006304642,0.0000324787,0.00001636075,0.000003421194,0.0001631994,0.000004017671,0.9948994,0.001201999,0.00004955157,0.003417727],"study_design_scores_gemma":[0.0009840674,0.00002606744,0.00001314487,0.0001005324,0.00004686439,0.0002684354,0.0004659991,0.000601184,0.9961649,0.0003905847,0.0007067847,0.0002314623],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9725839,0.0101796,0.003555331,0.007610432,0.0005896435,0.0001845291,0.00005703334,0.00005180474,0.005187722],"genre_scores_gemma":[0.9973226,0.0001090872,0.0002093528,0.0003695552,0.0005523923,0.00002072695,0.000004269602,0.00002731393,0.001384756],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02473864,"threshold_uncertainty_score":0.8462864,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01149241450688706,"score_gpt":0.2582826083630815,"score_spread":0.2467901938561945,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}