{"id":"W2057465974","doi":"10.1139/v00-184","title":"Pressure effects and solvent dynamics in the electrochemical kinetics of the tris(hexafluoroacetylacetonato)ruthenium(III)/(II) couple in nonaqueous solvents","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Research Council Canada; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Activation energy; Propylene carbonate; Solvent; Acetonitrile; Reaction rate constant; Diffusion; Kinetics; Electrochemistry; Acetone; Inorganic chemistry; Physical chemistry; Electrode; Thermodynamics; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001982832,0.0001876286,0.0003478273,0.00004665346,0.00007656348,0.00002745302,0.0007002499,0.0002107963,0.00007513665],"category_scores_gemma":[0.0001316925,0.0001323134,0.0001699414,0.0003866227,0.00017044,0.00003486552,0.00003887343,0.0007894082,2.631242e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002702856,"about_ca_system_score_gemma":0.0003049973,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005131277,"about_ca_topic_score_gemma":0.003788209,"domain_scores_codex":[0.9985649,0.00002092259,0.0005536674,0.0001870449,0.0002784995,0.0003949828],"domain_scores_gemma":[0.9988872,0.0001490794,0.0003188026,0.0003338309,0.00008706498,0.0002240223],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003163299,0.0001526777,0.01055799,0.0001515617,0.00006676857,0.00002830038,0.000290905,0.00003557511,0.9880095,0.00005785102,0.0002602335,0.0003569818],"study_design_scores_gemma":[0.001123919,0.00002959367,0.0006246486,0.0002314155,0.000133122,0.0003612246,0.0003653101,0.001685193,0.9904144,0.000909711,0.003920096,0.0002013252],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941501,0.0027444,0.00003918135,0.001102528,0.00001245045,0.00007730324,0.0000118574,0.000002534355,0.001859664],"genre_scores_gemma":[0.999219,0.0001550905,0.00003784776,0.00009983165,0.00008754534,0.00001174511,0.00001283149,0.00001575978,0.0003603325],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009933345,"threshold_uncertainty_score":0.5395583,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003435868785550176,"score_gpt":0.1933599279199873,"score_spread":0.1899240591344371,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}