{"id":"W2057541417","doi":"10.1016/j.poly.2006.06.032","title":"Highly luminescent Eu(III) complexes with 2,4,6-tri(2-pyridyl)-1,3,5-triazine ligand: Synthesis, structural characterization, and photoluminescence studies","year":2006,"lang":"en","type":"article","venue":"Polyhedron","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":54,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"Division of Chemistry; American Chemical Society Petroleum Research Fund; National Science Foundation","keywords":"Chemistry; Square antiprism; Ligand (biochemistry); Crystallography; Europium; Lanthanide; Luminescence; Photoluminescence; Steric effects; Coordination sphere; Quantum yield; Crystal structure; Coordination complex; Triazine; Photochemistry; Stereochemistry; Fluorescence; Ion; Metal; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001697783,0.0002056451,0.0002043962,0.0001251529,0.0001709178,0.0004426001,0.0003695137,0.0002894022,0.0009228394],"category_scores_gemma":[0.0002963939,0.0001893482,0.00009798665,0.0001573543,0.0002094082,0.0002615601,0.0002288747,0.0002510618,0.0002979363],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003163588,"about_ca_system_score_gemma":0.0001015196,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005145065,"about_ca_topic_score_gemma":0.0006832982,"domain_scores_codex":[0.9998631,0.00002812046,0.000008835661,0.00003270778,0.00003741339,0.00002980611],"domain_scores_gemma":[0.9998957,0.00002127538,0.00003057785,0.00001506007,0.00001821782,0.00001907573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000139965,0.00002245197,0.0001092217,0.00004122694,0.000006604292,0.00004584068,0.00003652062,0.0001087434,0.9978307,0.0002869804,0.0001044242,0.001267281],"study_design_scores_gemma":[0.00001717846,0.00007923977,0.0004469496,0.000002366452,0.000006165168,0.0001161278,0.000009158501,0.0004336323,0.9977406,0.000020506,0.001124656,0.000003541432],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.99029,0.001004293,0.005913886,0.00008276248,0.00001396209,0.00002346424,0.0001201515,0.0001338997,0.002417688],"genre_scores_gemma":[0.9919201,0.0002949924,0.002986458,0.00003743786,0.000004920769,0.0000191237,0.0002169287,0.00004773074,0.004472228],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009228394,"threshold_uncertainty_score":0.003087163,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01462216511637264,"score_gpt":0.2390656298083703,"score_spread":0.2244434646919976,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}