{"id":"W2057541417","doi":"10.1016/j.poly.2006.06.032","title":"Highly luminescent Eu(III) complexes with 2,4,6-tri(2-pyridyl)-1,3,5-triazine ligand: Synthesis, structural characterization, and photoluminescence studies","year":2006,"lang":"en","type":"article","venue":"Polyhedron","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":54,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"Division of Chemistry; American Chemical Society Petroleum Research Fund; National Science Foundation","keywords":"Chemistry; Square antiprism; Ligand (biochemistry); Crystallography; Europium; Lanthanide; Luminescence; Photoluminescence; Steric effects; Coordination sphere; Quantum yield; Crystal structure; Coordination complex; Triazine; Photochemistry; Stereochemistry; Fluorescence; Ion; Metal; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001964707,0.0003500118,0.0005431481,0.0001207213,0.0003574829,0.0001795222,0.000214349,0.00005880051,0.0001218589],"category_scores_gemma":[0.00003269837,0.0002520876,0.00005102735,0.0002533387,0.0003722736,0.0004644659,0.00007335149,0.00008252441,0.00004223899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003890331,"about_ca_system_score_gemma":0.00003514924,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005414686,"about_ca_topic_score_gemma":0.0003171742,"domain_scores_codex":[0.9980837,0.0000891248,0.0004629879,0.000532715,0.0003954024,0.0004360603],"domain_scores_gemma":[0.999075,0.0001298739,0.0002188591,0.0002950133,0.0001793345,0.0001019473],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001862385,0.00004444367,0.003506735,0.000107878,0.00002639459,0.00002403516,0.0001652186,0.000005100569,0.9947767,0.0009067426,0.0001182438,0.0001322556],"study_design_scores_gemma":[0.0008329498,0.0001018348,0.06605779,0.0001508476,0.0001010745,0.0001093592,0.00009351497,0.00008771208,0.9312059,0.0001657956,0.0006868133,0.0004063704],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968417,0.0009238343,0.0003954795,0.0007484982,0.0003122732,0.0003453841,0.0001536389,0.0001890466,0.00009010174],"genre_scores_gemma":[0.9982327,0.0001351297,0.0006243978,0.0001708946,0.0003264374,0.00004631448,0.0001005536,0.000032223,0.0003313082],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06357078,"threshold_uncertainty_score":0.9999931,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01462216511637264,"score_gpt":0.2390656298083703,"score_spread":0.2244434646919976,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}