{"id":"W2057597919","doi":"10.1016/s1386-1425(99)00136-5","title":"Pressure-tuning infrared and Raman spectroscopy of Group 14 tetraphenyl compounds","year":2000,"lang":"en","type":"article","venue":"Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy","topic":"Chemical Thermodynamics and Molecular Structure","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"Raman spectroscopy; Infrared spectroscopy; Infrared; Diamond anvil cell; Ring (chemistry); Chemistry; Group (periodic table); Ambient pressure; Analytical Chemistry (journal); Crystallography; High pressure; Materials science; Organic chemistry; Thermodynamics; Optics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001575211,0.0008125046,0.0009297366,0.0001892094,0.0002418858,0.0002141371,0.0005471635,0.0004218759,0.001086841],"category_scores_gemma":[0.00003277267,0.0008096429,0.0003647974,0.0004309364,0.0006173881,0.0001341603,0.0002252112,0.0007045731,0.000004161122],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006296,"about_ca_system_score_gemma":0.00006249763,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003549178,"about_ca_topic_score_gemma":0.000009087425,"domain_scores_codex":[0.9963154,0.00008110496,0.0007272566,0.001239268,0.0006293929,0.001007551],"domain_scores_gemma":[0.9981664,0.00004617023,0.0002623473,0.0009948618,0.00006937354,0.0004608567],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003841276,0.0001752192,0.0002007501,0.0002179099,0.0004528499,0.0001024914,0.0001253503,0.00000200205,0.9949222,0.002900166,0.0001806481,0.0003362686],"study_design_scores_gemma":[0.001906609,0.0002820576,0.0001784518,0.0001548422,0.0003453253,0.0002473683,0.00004371078,0.0008699439,0.9789604,0.006680151,0.009469673,0.0008614812],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9647087,0.003274753,0.00175172,0.0002723245,0.00007541813,0.0003088338,0.0001188986,0.0001775949,0.02931175],"genre_scores_gemma":[0.9895601,0.001026359,0.008340939,0.0002863777,0.0001396124,0.00002639936,0.0002150655,0.0001384282,0.0002667702],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02904498,"threshold_uncertainty_score":0.9998263,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003928545263288661,"score_gpt":0.2175168033789124,"score_spread":0.2135882581156238,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}