{"id":"W2057828836","doi":"10.1016/j.ica.2007.12.003","title":"Ruthenium hydrogenation catalysts with P–N–N–P ligands derived from 1,3-diaminopropane and the formation of a β-diiminate complex by a base-induced isomerization","year":2008,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Ruthenium; Isomerization; Acetophenone; Benzonitrile; Ligand (biochemistry); Catalysis; Medicinal chemistry; Coordination complex; Stereochemistry; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000126154,0.0002414291,0.000381654,0.0001234392,0.000247939,0.00003410345,0.0002987338,0.00013706,0.0001287339],"category_scores_gemma":[0.0001462482,0.0001730365,0.00007610646,0.0006130514,0.0002271804,0.0002975812,0.0000859162,0.0001673293,0.000009477202],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006416297,"about_ca_system_score_gemma":0.0000623709,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001861818,"about_ca_topic_score_gemma":0.00002427108,"domain_scores_codex":[0.9984697,0.00004508392,0.0005023099,0.0003324113,0.0004441971,0.0002063426],"domain_scores_gemma":[0.9985824,0.0001861026,0.0005112363,0.0004609833,0.0001579861,0.0001012495],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001557318,0.00009580409,0.0002354546,0.00002992686,0.0001180751,0.00000122172,0.002310507,0.00000105282,0.9966246,0.00001731109,0.0001670204,0.0002432293],"study_design_scores_gemma":[0.002788989,0.00003115231,0.0008124364,0.00002199456,0.0001725384,0.00006100286,0.0003837886,0.007491323,0.9878674,0.0000266003,0.0001196841,0.0002231408],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973795,0.00007047219,0.0002791823,0.0008610148,0.00001503748,0.0001831191,0.0001466413,0.00008211843,0.0009829254],"genre_scores_gemma":[0.9978703,0.0001459193,0.0001421203,0.0001438393,0.00004185958,0.00003079582,0.00151957,0.00003732298,0.00006822991],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008757316,"threshold_uncertainty_score":0.7056223,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01306713517975016,"score_gpt":0.1975503719375868,"score_spread":0.1844832367578366,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}