{"id":"W2057974524","doi":"10.1016/s0008-6215(99)00314-6","title":"Synthesis of 4-deoxy analogues of 2-acetamido-2-deoxy-d-glucose and 2-acetamido-2-deoxy-d-xylose and their effects on glycoconjugate biosynthesis","year":2000,"lang":"en","type":"article","venue":"Carbohydrate Research","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":false,"ca_institutions":"Kingston General Hospital; Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Glycoconjugate; Xylose; Biosynthesis; Stereochemistry; Acetylation; Substituent; Hepatocyte; Biochemistry; In vitro; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001786543,0.0008420722,0.001613264,0.0005742164,0.0003790946,0.0001533581,0.0008196867,0.0007116458,0.001012334],"category_scores_gemma":[0.001492506,0.0007245446,0.0003814714,0.001116819,0.00178175,0.0002422199,0.0003423413,0.0009207238,0.00004481313],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001539539,"about_ca_system_score_gemma":0.0001854364,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003169256,"about_ca_topic_score_gemma":0.00002414784,"domain_scores_codex":[0.9946206,0.0006084723,0.001058878,0.001386141,0.001025196,0.00130075],"domain_scores_gemma":[0.9917237,0.005263948,0.0003047842,0.001671583,0.0004076689,0.0006283537],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007646015,0.0003403075,0.0005808069,0.00233962,0.0004116635,0.00007538893,0.0006119464,0.00001144144,0.917214,0.000119681,0.00009000798,0.07744052],"study_design_scores_gemma":[0.0007979508,0.000209432,0.0004460742,0.001268508,0.0001451652,0.00002619643,0.0007157319,0.0006805381,0.9934086,0.0006529347,0.0009939976,0.0006549046],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9800944,0.003666641,0.000001185876,0.0003991059,0.00004714262,0.0004107732,0.0003745961,0.0001185398,0.01488764],"genre_scores_gemma":[0.9906678,0.00769411,0.00007237817,0.00003469729,0.000232933,0.0002018255,0.00003469323,0.0001405186,0.0009209996],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07678562,"threshold_uncertainty_score":0.9999009,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02366211767787389,"score_gpt":0.2718338944617887,"score_spread":0.2481717767839148,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}