{"id":"W2058007033","doi":"10.1021/ic801725u","title":"Stability of [2]Pseudorotaxanes Templated Through Second-Sphere Coordination","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Coordination sphere; Stability (learning theory); Crystallography; Stereochemistry; Nanotechnology; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001416917,0.0002874887,0.0001696652,0.0001159496,0.0001072391,0.0003558187,0.000302719,0.0002267303,0.001060535],"category_scores_gemma":[0.0004620256,0.000173126,0.00007976789,0.0001620203,0.000168784,0.0002527522,0.0001469176,0.0002553044,0.0003194654],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002153186,"about_ca_system_score_gemma":0.0001543699,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004016581,"about_ca_topic_score_gemma":0.000769905,"domain_scores_codex":[0.9998015,0.00003430863,0.00001258567,0.00005484941,0.00006327565,0.00003350675],"domain_scores_gemma":[0.9998161,0.00003158593,0.00006826343,0.00001791191,0.00003083951,0.00003529178],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001384309,0.00001480723,0.000211072,0.00004496086,0.00001066327,0.00003808679,0.00003971757,0.0006040641,0.9970336,0.0001945772,0.00005004289,0.001619942],"study_design_scores_gemma":[0.00001795692,0.0004012359,0.001658427,0.000003617802,0.000006288647,0.00009971116,0.00002188096,0.001610422,0.994891,0.00003591081,0.001242148,0.00001146766],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979141,0.0003485175,0.0006919065,0.00001440057,0.000008631182,0.000009470426,0.00007705017,0.00004597341,0.0008898556],"genre_scores_gemma":[0.9978533,0.0001924866,0.000840017,0.00001422067,0.000003329436,0.0000160068,0.0002774869,0.00001593779,0.0007872802],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001060535,"threshold_uncertainty_score":0.003547907,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01388780208857276,"score_gpt":0.2287992717966378,"score_spread":0.214911469708065,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}