{"id":"W2058323342","doi":"10.1021/om0105167","title":"Metallaaziridine Complexes of Tantalum Derived from 1,8-Bis(isopropylamino)naphthalene via β-H Activation","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Yield (engineering); Tantalum; Metathesis; Salt metathesis reaction; Stereochemistry; Bicyclic molecule; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002541231,0.0004407252,0.0007289558,0.0000915218,0.00009993545,0.00003746846,0.0006177835,0.0002931192,0.03094573],"category_scores_gemma":[0.0004703891,0.0004467158,0.0002241472,0.0005754079,0.0002363406,0.0001858082,0.0002289695,0.0002774954,0.0000667189],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000159419,"about_ca_system_score_gemma":0.0001002826,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001534836,"about_ca_topic_score_gemma":0.000008022252,"domain_scores_codex":[0.9975553,0.00005747825,0.0007519976,0.0006431958,0.0005521106,0.0004399085],"domain_scores_gemma":[0.9976891,0.0004058725,0.0004934492,0.001057737,0.0001729262,0.0001809496],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006548189,0.000284657,0.002462259,0.00008641139,0.000272906,0.0000150567,0.0001258141,0.000004146428,0.9905816,0.00005785721,0.00003261474,0.006011154],"study_design_scores_gemma":[0.0007858754,0.00002370667,0.002401113,0.00005538675,0.0001752315,0.00007492801,0.0002269234,0.0001748651,0.9896783,0.000879952,0.005079039,0.0004446333],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9752452,0.0002737445,0.008584751,0.0002355434,0.0001541088,0.0001055314,0.00009576212,0.0001764853,0.01512889],"genre_scores_gemma":[0.9815318,0.000147069,0.01523412,0.00004045121,0.0003099241,0.00001415674,0.0002689358,0.0001129331,0.0023406],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03087901,"threshold_uncertainty_score":0.9997985,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02544592973282759,"score_gpt":0.2607139678196599,"score_spread":0.2352680380868324,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}