{"id":"W2058477243","doi":"10.1139/v03-131","title":"The photochemistry of indenyl alcohols and esters: Substituent effects on the competition between ion- and radical-derived products","year":2003,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Photochemistry; Solvolysis; Decarboxylation; Substituent; Heterolysis; Radical; Singlet state; Cyclohexane; Methanol; Radical ion; Excited state; Reactivity (psychology); Homolysis; Medicinal chemistry; Ion; Organic chemistry; Hydrolysis; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002285574,0.0004034342,0.0001929352,0.0001387487,0.0001649125,0.0002672972,0.0002465533,0.0002919693,0.002307113],"category_scores_gemma":[0.0003421238,0.0001445498,0.0001699682,0.0001569273,0.0002120143,0.000401971,0.0001473002,0.000371057,0.0003812216],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000236225,"about_ca_system_score_gemma":0.0001781807,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007035268,"about_ca_topic_score_gemma":0.001254994,"domain_scores_codex":[0.9998797,0.0000177944,0.000005748824,0.00002520902,0.0000315062,0.00004012111],"domain_scores_gemma":[0.9997578,0.0001023109,0.00004826367,0.00002064866,0.00003740702,0.00003352498],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000121151,0.00000876898,0.0001485835,0.00004221778,0.000002850644,0.00004352968,0.00002411549,0.00005776912,0.9980982,0.00005930478,0.00001072666,0.001382794],"study_design_scores_gemma":[0.000003388067,0.0001116382,0.0005533959,0.00000132537,0.000003514894,0.00004666514,0.000008018319,0.00007457665,0.998904,0.00001270694,0.0002785176,0.000002145902],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945345,0.00140284,0.001202793,0.0000351777,0.0000124191,0.00002120007,0.00008608266,0.0000285737,0.002676495],"genre_scores_gemma":[0.9961458,0.0007465195,0.001042135,0.00002123331,0.000005133656,0.000009616117,0.0001347441,0.00001875662,0.001875989],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002307113,"threshold_uncertainty_score":0.007718086,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01154327972344571,"score_gpt":0.2122739463503816,"score_spread":0.2007306666269359,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}