{"id":"W2058545011","doi":"10.1021/ja1043006","title":"Concerning the Mechanism of the FeCl<sub>3</sub>-Catalyzed α-Oxyamination of Aldehydes: Evidence for a Non-SOMO Activation Pathway","year":2010,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":154,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Institute of General Medical Sciences; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Catalysis; Mechanism (biology); Reaction mechanism; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003240498,0.0004273089,0.0001400377,0.0001548812,0.0001814702,0.0002187364,0.0003268079,0.0003687493,0.001195414],"category_scores_gemma":[0.0004227331,0.00007828059,0.000166496,0.00006517692,0.0004459348,0.0006148899,0.0001590995,0.0004444827,0.0003624785],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002463561,"about_ca_system_score_gemma":0.0001381875,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003319606,"about_ca_topic_score_gemma":0.0003733031,"domain_scores_codex":[0.9999306,0.00001406828,0.000004434463,0.00001521835,0.00001795629,0.00001763052],"domain_scores_gemma":[0.9997688,0.00008912399,0.00005835293,0.00002083151,0.00004788875,0.00001500174],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004188112,0.00003907994,0.00168256,0.0002670342,0.00002127678,0.0006552531,0.0001438397,0.0004166709,0.9825392,0.002658781,0.00008125633,0.01107622],"study_design_scores_gemma":[0.00000812835,0.0001686327,0.002055853,0.00001194433,0.00002360729,0.0006282979,0.0000600782,0.001899204,0.992631,0.001153813,0.001349588,0.000009762926],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9721509,0.004417244,0.01798929,0.0004879973,0.00007955709,0.00004935866,0.0001079194,0.00007074685,0.004647121],"genre_scores_gemma":[0.9949855,0.001060002,0.002800893,0.00003910557,0.00001623993,0.000007465849,0.00004564955,0.000004392857,0.001040857],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001195414,"threshold_uncertainty_score":0.003998995,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02179991265662942,"score_gpt":0.2704823100021839,"score_spread":0.2486823973455544,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}