{"id":"W2058584342","doi":"10.1039/b210570e","title":"Definitive identification of cysteine and glutathione complexes of bismuth by mass spectrometry: assessing the biochemical fate of bismuth pharmaceutical agents","year":2002,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":228,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Bismuth; Cysteine; Glutathione; Mass spectrometry; Chemistry; Biomolecule; Methionine; Homocysteine; Electrospray mass spectrometry; Combinatorial chemistry; Electrospray; Biochemistry; Chromatography; Organic chemistry; Amino acid; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002079736,0.0001575129,0.000346896,0.0000700216,0.0001044362,0.0000315863,0.0006759266,0.0001078276,0.0002154828],"category_scores_gemma":[0.0002556086,0.0001365664,0.00009609446,0.0004005143,0.0007995364,0.0001082744,0.0002826727,0.0002392389,0.00000279089],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003975828,"about_ca_system_score_gemma":0.00001341716,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008888544,"about_ca_topic_score_gemma":1.588732e-7,"domain_scores_codex":[0.9985105,0.00008126165,0.0007763133,0.000211641,0.0002629455,0.0001573818],"domain_scores_gemma":[0.9976946,0.0005899007,0.0005676646,0.0009187214,0.000161094,0.00006806562],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007402581,0.0004023642,0.0005964873,0.0001308676,0.00007895848,8.575181e-8,0.0002854779,1.863863e-7,0.9971172,0.0006581203,0.00007943648,0.0006434664],"study_design_scores_gemma":[0.0003406532,0.00001018637,0.0006647632,0.00008879107,0.0001333567,0.000004622246,0.0003434452,0.003342573,0.9943886,0.0003039508,0.0002574692,0.0001215885],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940003,0.001649567,0.001007121,0.0009155872,0.00001308306,0.00009624253,0.0002799977,0.00002546606,0.002012591],"genre_scores_gemma":[0.9973141,0.0009155179,0.001350613,0.00001901573,0.00001673742,0.00001556282,0.0002958597,0.00001978335,0.00005283041],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003342386,"threshold_uncertainty_score":0.5569018,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05867318178802792,"score_gpt":0.3059195446098753,"score_spread":0.2472463628218474,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}