{"id":"W2058810851","doi":"10.1002/chem.200304886","title":"Synthesis of Five Generations of Redox‐Stable Pentamethylamidoferrocenyl Dendrimers and Comparison of Amidoferrocenyl‐ and Pentamethylamidoferrocenyl Dendrimers as Electrochemical Exoreceptors for the Selective Recognition of H<sub>2</sub>PO<sub>4</sub><sup>−</sup>, HSO<sub>4</sub><sup>−</sup>, and Adenosine 5′‐Triphosphate (ATP) Anions: Stereoelectronic and Hydrophobic Roles of Cyclopentadienyl Permethylation","year":2003,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":100,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Université de Bordeaux; Institut Universitaire de France; Centre National de la Recherche Scientifique; Institut national de la recherche scientifique","keywords":"Dendrimer; Chemistry; Titration; Electrochemistry; Redox; Adsorption; Crystallography; Decomposition; Stereochemistry; Physical chemistry; Inorganic chemistry; Polymer chemistry; Organic chemistry; Electrode","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001232541,0.0002807768,0.0001861303,0.0001188852,0.00008570544,0.0002199035,0.0002276191,0.0003175375,0.0004639728],"category_scores_gemma":[0.0002316687,0.0001360658,0.0001773182,0.0001276075,0.0001629745,0.0002280163,0.0001615075,0.00024359,0.0001981878],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003436687,"about_ca_system_score_gemma":0.000118802,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004759403,"about_ca_topic_score_gemma":0.0008864644,"domain_scores_codex":[0.9999036,0.000007263239,0.00001074945,0.00002858102,0.00002597174,0.00002385766],"domain_scores_gemma":[0.9998491,0.00001566793,0.00005307251,0.00001886632,0.00002833351,0.00003499011],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004083205,0.000005561885,0.00007159854,0.00001303761,0.000002785283,0.00001673058,0.00001137561,0.00005291306,0.9987512,0.00002956698,0.00001031754,0.0009940763],"study_design_scores_gemma":[0.000006661145,0.0001782613,0.001448712,0.000002502369,0.00001181639,0.0001223966,0.000009245509,0.0003585379,0.997009,0.00001164643,0.0008375711,0.000003813373],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948823,0.0005786272,0.003522608,0.00004162228,0.00001661483,0.00003486295,0.0001122879,0.00005530498,0.000755701],"genre_scores_gemma":[0.9885373,0.0004449543,0.007753592,0.00003626751,0.000006077653,0.00004367838,0.0003149009,0.00001998941,0.00284318],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004759403,"threshold_uncertainty_score":0.002493501,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01141467798491161,"score_gpt":0.2316611840673799,"score_spread":0.2202465060824683,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}