{"id":"W2058833602","doi":"10.1016/j.jasms.2007.02.005","title":"An enzyme derivatized polydimethylsiloxane (PDMS) membrane for use in membrane introduction mass spectrometry (MIMS)","year":2007,"lang":"en","type":"article","venue":"Journal of the American Society for Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Vancouver Island University","funders":"British Columbia Knowledge Development Fund; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Polydimethylsiloxane; Membrane; Chromatography; Immobilized enzyme; Mass spectrometry; Organic chemistry; Enzyme; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000364331,0.0006772901,0.0002750207,0.0003445392,0.0002736593,0.000307141,0.0004218471,0.0006525366,0.001472675],"category_scores_gemma":[0.0004055835,0.0003200797,0.0004258097,0.000243544,0.000276005,0.0003593718,0.0002281281,0.0006457139,0.001006447],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004967187,"about_ca_system_score_gemma":0.000563141,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005321715,"about_ca_topic_score_gemma":0.0007464912,"domain_scores_codex":[0.9997439,0.00002587697,0.0000238627,0.00005654653,0.000122819,0.00002697286],"domain_scores_gemma":[0.9998236,0.00005295947,0.00003397766,0.00002877581,0.00003633817,0.00002433722],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001385833,0.000006904359,0.00007487084,0.00003059561,0.000002751741,0.00005059227,0.00000366948,0.00002564517,0.9980187,0.0000776713,0.00005932557,0.001635369],"study_design_scores_gemma":[0.000004583097,0.00004686204,0.0008380502,0.000003355605,0.000007338611,0.0003392326,0.000003851688,0.000623059,0.9938612,0.00003009973,0.004237147,0.000005164057],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6567785,0.007187118,0.3183197,0.001747121,0.001031792,0.0007539562,0.002762593,0.001977434,0.009441802],"genre_scores_gemma":[0.5714417,0.005605908,0.4090524,0.0007003944,0.0001348816,0.0004021257,0.002705905,0.000111184,0.009845492],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001472675,"threshold_uncertainty_score":0.004926622,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01426633980667239,"score_gpt":0.2838848882147114,"score_spread":0.269618548408039,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}