{"id":"W2058863333","doi":"10.1002/chin.200148118","title":"ChemInform Abstract: A Mild Procedure for the Reduction of Pyridine N‐Oxides to Piperidines Using Ammonium Formate.","year":2001,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"BioPhage Pharma (Canada)","funders":"","keywords":"Chemistry; Pyridine; Ammonium formate; Reduction (mathematics); Formate; Combinatorial chemistry; Ammonium; Service (business); Organic chemistry; Acetonitrile; Business","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003268802,0.001084441,0.0004016483,0.0008239312,0.0006435819,0.000219133,0.0007486456,0.0002947705,0.01733054],"category_scores_gemma":[0.0003154592,0.000533341,0.0003021389,0.0004122605,0.0002150777,0.0005353428,0.0004704126,0.001114706,0.01123766],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002574496,"about_ca_system_score_gemma":0.0007073862,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008200164,"about_ca_topic_score_gemma":0.002615707,"domain_scores_codex":[0.9997656,0.00002814337,0.00001833335,0.00003584682,0.0001105361,0.00004159899],"domain_scores_gemma":[0.9999154,0.00001620019,0.00001645527,0.00001683978,0.00001883683,0.00001629396],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002645627,0.0001033538,0.0001264176,0.002093121,0.00004548974,0.0005108633,0.000168448,0.0003295552,0.8983491,0.001466737,0.02632154,0.07022075],"study_design_scores_gemma":[0.00006295768,0.0004223033,0.001392263,0.00009020542,0.000040256,0.001102951,0.000031222,0.0004744549,0.8014213,0.0005766469,0.1943398,0.0000456145],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.1912201,0.06277183,0.5133513,0.002519061,0.003919935,0.003014501,0.0242377,0.01921935,0.1797463],"genre_scores_gemma":[0.5605556,0.05450533,0.1532014,0.001389813,0.0008469562,0.001880733,0.03051158,0.001690758,0.1954178],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01733054,"threshold_uncertainty_score":0.05797637,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03233737041936668,"score_gpt":0.2708479850563009,"score_spread":0.2385106146369342,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}