{"id":"W2058992785","doi":"10.1016/j.carres.2009.03.008","title":"Convenient approaches to synthesis of furanoid sugar-aza-crown ethers from C-ribosyl azido aldehyde via a reductive amination/amidation","year":2009,"lang":"en","type":"article","venue":"Carbohydrate Research","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":false,"ca_institutions":"Institute for Biological Sciences","funders":"National Science Council","keywords":"Chemistry; Reductive amination; Aldehyde; Anomer; Disaccharide; Amide; Amination; Organic chemistry; Ether; Crown ether; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000416059,0.00056299,0.0002948865,0.0003032893,0.0002968193,0.0003276427,0.0003966771,0.0002707382,0.001302973],"category_scores_gemma":[0.0001803591,0.0002485081,0.000279294,0.0002825269,0.0002714039,0.0004410299,0.0004512306,0.0009198739,0.000601124],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004932097,"about_ca_system_score_gemma":0.0004179556,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000590164,"about_ca_topic_score_gemma":0.001784201,"domain_scores_codex":[0.9998357,0.00001948872,0.00001664874,0.00002309452,0.00005512477,0.00004990453],"domain_scores_gemma":[0.9999244,0.00001163009,0.00001797746,0.00001543581,0.00001143154,0.00001908389],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001225722,0.00007229194,0.0001286363,0.0001842421,0.00002155386,0.0003760045,0.0001705592,0.0005778822,0.9772205,0.004614167,0.0002372342,0.01627442],"study_design_scores_gemma":[0.00003484217,0.000302159,0.0005913521,0.00001078657,0.00002660705,0.0003960794,0.0000322254,0.0007374621,0.9840214,0.000718671,0.01310611,0.00002228764],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8526073,0.01113372,0.1103048,0.0006037719,0.0003231309,0.0004160079,0.001019636,0.0004861453,0.02310541],"genre_scores_gemma":[0.9394604,0.006952421,0.04771189,0.0001006238,0.00007332666,0.0001232043,0.0005794383,0.0000561064,0.004942598],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001302973,"threshold_uncertainty_score":0.004358947,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1182478780730072,"score_gpt":0.3070077109821446,"score_spread":0.1887598329091374,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}