{"id":"W2059058178","doi":"10.1002/hlca.200490027","title":"Photocycloaddition of Some Difluoro(aminoenonato)boron Complexes with Arylalkenes","year":2004,"lang":"en","type":"article","venue":"Helvetica Chimica Acta","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Cyclobutane; Azetidine; Boron; Stereoselectivity; Reactivity (psychology); Singlet state; Molecular orbital; Stereochemistry; Photochemistry; Medicinal chemistry; Computational chemistry; Molecule; Organic chemistry; Ring (chemistry); Catalysis; Excited state","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001058883,0.0002880745,0.0002097363,0.0002087839,0.000181389,0.0002183278,0.0001805503,0.0002639996,0.001950121],"category_scores_gemma":[0.0001485219,0.0001304004,0.0001557845,0.0001731113,0.0001635046,0.0001715408,0.0001481785,0.0002697321,0.0002833926],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003311583,"about_ca_system_score_gemma":0.0001739388,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001308077,"about_ca_topic_score_gemma":0.002302278,"domain_scores_codex":[0.9998952,0.00001100213,0.00000668248,0.00002083379,0.00002230297,0.0000439647],"domain_scores_gemma":[0.9999532,0.00001015618,0.00001308844,0.000005703613,0.000005344265,0.00001246475],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001884783,0.00002741039,0.00009441521,0.0001068197,0.000006751648,0.0001124552,0.00005675314,0.0003155568,0.9962445,0.0005176989,0.00008980794,0.002239288],"study_design_scores_gemma":[0.00002279323,0.0002733989,0.0006309793,0.00000711422,0.000007942468,0.00009118221,0.00001688777,0.0003958897,0.9961372,0.00003789508,0.002371523,0.000007067122],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908077,0.001360103,0.00118543,0.00006390945,0.00003960134,0.00004073112,0.0001569521,0.00005220407,0.006293489],"genre_scores_gemma":[0.9966312,0.000612234,0.0008014844,0.00002258597,0.000005537633,0.00001687955,0.00007221117,0.00001242477,0.001825411],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001950121,"threshold_uncertainty_score":0.006523788,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04632021301367568,"score_gpt":0.3529696620183931,"score_spread":0.3066494490047175,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}