{"id":"W2059264975","doi":"10.1021/om030262k","title":"Binuclear and Starburst Organoplatinum(II) Complexes of 2,2‘-Dipyridylamino Derivative Ligands:  Structures, Fluxionality, and Luminescence","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Ligand (biochemistry); Phosphorescence; Tris; Benzene; Intramolecular force; Biphenyl; Crystal structure; Chelation; Crystallography; Luminescence; Stereochemistry; Medicinal chemistry; Photochemistry; Fluorescence; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008240564,0.0001724442,0.0001822077,0.00007969033,0.000125174,0.0003023594,0.0004001455,0.0002648664,0.0009427404],"category_scores_gemma":[0.0001174827,0.0001323547,0.00007411524,0.00009538608,0.0001422409,0.0001719443,0.0002686964,0.0003040742,0.0002184877],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005513219,"about_ca_system_score_gemma":0.0001218834,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007612878,"about_ca_topic_score_gemma":0.001094306,"domain_scores_codex":[0.9999245,0.00001237241,0.000004521091,0.00002204021,0.00001560549,0.00002085531],"domain_scores_gemma":[0.9999415,0.000009206861,0.00001330475,0.000006333513,0.000008372964,0.00002124141],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001031658,0.000009642687,0.0001259822,0.00004172227,0.00000413744,0.00002335638,0.00002499678,0.0001591885,0.9979994,0.0002900381,0.00006285855,0.001155548],"study_design_scores_gemma":[0.00001652459,0.00008300538,0.0006502061,0.000002941093,0.000006449695,0.0001097918,0.00001367874,0.001348823,0.9960591,0.00002570266,0.001679954,0.000003947706],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948741,0.000619697,0.002472159,0.00006188705,0.000009003511,0.00001034379,0.00005961844,0.00006819662,0.001824942],"genre_scores_gemma":[0.994464,0.0002464065,0.002250213,0.00004692732,0.000001499635,0.00001427007,0.0001430078,0.00002470647,0.002808934],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009427404,"threshold_uncertainty_score":0.004000187,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01482582148068612,"score_gpt":0.220664143351491,"score_spread":0.2058383218708049,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}