{"id":"W2059264975","doi":"10.1021/om030262k","title":"Binuclear and Starburst Organoplatinum(II) Complexes of 2,2‘-Dipyridylamino Derivative Ligands:  Structures, Fluxionality, and Luminescence","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Ligand (biochemistry); Phosphorescence; Tris; Benzene; Intramolecular force; Biphenyl; Crystal structure; Chelation; Crystallography; Luminescence; Stereochemistry; Medicinal chemistry; Photochemistry; Fluorescence; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00028894,0.0002352462,0.0004122093,0.0001000098,0.0002667124,0.00007988784,0.0001643734,0.00007462523,0.001398308],"category_scores_gemma":[0.0001314119,0.0001984679,0.00003811612,0.0003178437,0.0005071494,0.0002816356,0.0001297341,0.00009839152,0.00001218384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001428764,"about_ca_system_score_gemma":0.00005122096,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004826509,"about_ca_topic_score_gemma":0.00003009774,"domain_scores_codex":[0.9985864,0.00008015035,0.0003750875,0.0003930364,0.0003031135,0.0002622397],"domain_scores_gemma":[0.9992071,0.0001160472,0.0001637766,0.0002492961,0.0001353027,0.0001284783],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000020105,0.00005203954,0.002172701,0.00009022688,0.00002407946,0.000004701155,0.000698309,0.000002181251,0.946561,0.05027099,0.00003081572,0.00007289761],"study_design_scores_gemma":[0.0006202938,0.0001945069,0.02812906,0.00002910929,0.0000602961,0.00007275723,0.0003295261,0.00001716625,0.9564481,0.01229809,0.001496757,0.0003043493],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981382,0.0004800952,0.0003664549,0.0001055134,0.00009999079,0.0001716425,0.0001304889,0.00004723549,0.0004603898],"genre_scores_gemma":[0.9936477,0.0001053633,0.005927513,0.0001234555,0.00002686304,0.000002705521,0.00002442142,0.00002651544,0.000115472],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03797289,"threshold_uncertainty_score":0.9995145,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01482582148068612,"score_gpt":0.220664143351491,"score_spread":0.2058383218708049,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}