{"id":"W2059273225","doi":"10.1021/ja9077446","title":"Stabilizing Zr and Ti Cations by Interaction With a Ferrocenyl Fragment","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Agostic interaction; Cyclopentadienyl complex; Ligand (biochemistry); Stereochemistry; Metal; Crystallography; Medicinal chemistry; Catalysis; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007937264,0.0000947808,0.0002166062,0.000007000629,0.00007728685,0.00003419479,0.0001779654,0.00002151132,0.000318677],"category_scores_gemma":[0.00003463968,0.00005718791,0.0002030207,0.0001625008,0.0001327371,0.00007265405,0.0000343963,0.0002399065,5.194776e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001521941,"about_ca_system_score_gemma":0.00002918191,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001674137,"about_ca_topic_score_gemma":5.715085e-7,"domain_scores_codex":[0.9993302,0.000009236773,0.0002173112,0.000105092,0.0002213697,0.0001168069],"domain_scores_gemma":[0.9992171,0.00006815369,0.0004309767,0.0001533561,0.00005604518,0.00007436777],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002335164,0.0001101585,0.0006223383,0.000007008622,0.0001047621,2.317944e-7,0.000359785,0.000003527113,0.9815198,0.000003039247,0.001517092,0.01572898],"study_design_scores_gemma":[0.0004760595,0.00009687245,0.002932164,0.00009855549,0.0003305807,0.0001369471,0.006034408,0.0002604851,0.9656551,0.0001682086,0.023557,0.0002536504],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957263,0.0001790657,0.0001258443,0.003392749,0.000009609449,0.00001527974,0.000004400689,0.000007466408,0.0005392138],"genre_scores_gemma":[0.9983144,0.00008837308,0.0009640658,0.0003960722,0.00008421503,9.254705e-7,0.000001344586,0.000007307458,0.0001433162],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02203991,"threshold_uncertainty_score":0.348929,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008329218572471873,"score_gpt":0.2344508438014089,"score_spread":0.226121625228937,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}