{"id":"W2059420611","doi":"10.1021/om1006215","title":"Assembly of Tunable Supramolecular Organometallic Catalysts with Cyclodextrins","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Hydroformylation; Chemistry; Regioselectivity; Catalysis; Ligand (biochemistry); Supramolecular chemistry; Homogeneous; Homogeneous catalysis; Coordination sphere; Combinatorial chemistry; Rhodium; Heterogeneous catalysis; Organic chemistry; Polymer chemistry; Molecule; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001303997,0.0003016579,0.0002612498,0.0002561104,0.0001209411,0.0005186447,0.0002873073,0.0002286795,0.0009612161],"category_scores_gemma":[0.0002768607,0.000251229,0.0001871801,0.000142543,0.0001959247,0.0002151955,0.0002638552,0.0003884259,0.0004161024],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004211086,"about_ca_system_score_gemma":0.0001534585,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002884109,"about_ca_topic_score_gemma":0.0005051086,"domain_scores_codex":[0.9998634,0.00001178335,0.00001598611,0.00004688929,0.00003067901,0.0000313767],"domain_scores_gemma":[0.9998819,0.00002287732,0.00002719027,0.0000163463,0.0000155498,0.0000362205],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004878603,0.00002097423,0.00009609439,0.00002712134,0.00001125129,0.00003125449,0.00001536302,0.0003087989,0.997881,0.0001493876,0.00005132786,0.001358647],"study_design_scores_gemma":[0.00001289677,0.00004930326,0.0003179391,0.000001941742,0.00001228398,0.00003216385,0.000007057009,0.001967704,0.9964436,0.00002166989,0.001129061,0.000004410435],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9897026,0.0007235671,0.006375311,0.00007303275,0.0001013743,0.00006452633,0.0000920144,0.0003923045,0.002475408],"genre_scores_gemma":[0.9956897,0.0002047586,0.002517215,0.00004131608,0.00001160638,0.00002634779,0.00006722289,0.00003112136,0.001410733],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009612161,"threshold_uncertainty_score":0.003215611,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005596425132334677,"score_gpt":0.1951927878843984,"score_spread":0.1895963627520637,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}