{"id":"W2059435976","doi":"10.1021/jo016242e","title":"Synthesis of Syn and Anti Isomers of <i>trans</i>-Cyclopropyl Arginine","year":2002,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Chemistry; Cyclopropanation; Diazomethane; Hydrogenolysis; Pyrazoline; Arginine; Stereochemistry; Citrulline; Hydrolysis; Context (archaeology); Nitric oxide synthase; Nitric oxide; Organic chemistry; Amino acid; Biochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002053203,0.0001409624,0.0003767829,0.00001891331,0.00003566041,0.00000569564,0.000290119,0.0001168058,0.005032181],"category_scores_gemma":[0.0002362302,0.00009971568,0.0001245479,0.0001345833,0.0001461363,0.0000526774,0.0000415882,0.0003116648,0.000001043164],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003286879,"about_ca_system_score_gemma":0.00003310159,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003806181,"about_ca_topic_score_gemma":1.779396e-7,"domain_scores_codex":[0.9989441,0.000008278407,0.0005277023,0.00009200901,0.0002746253,0.0001532842],"domain_scores_gemma":[0.9987053,0.000274244,0.0005351646,0.0002711173,0.0001117079,0.0001024105],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003536508,0.000127621,0.00005742522,0.0003167137,0.0001102271,0.000005271481,0.0001679364,0.000002003954,0.9968635,0.000001968153,0.0002003926,0.002111559],"study_design_scores_gemma":[0.0003969645,0.00001339596,0.00001017022,0.000214069,0.0002350002,0.0005226665,0.0004933527,0.00002468227,0.9969954,0.00005832309,0.0009412635,0.00009468566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934406,0.001165129,0.0001100671,0.0002866993,0.00002985907,0.00001781278,0.00001560972,0.000007898253,0.004926297],"genre_scores_gemma":[0.996585,0.002619566,0.0002049268,0.00001141862,0.00009750234,4.648315e-7,5.723631e-7,0.0000214254,0.0004590964],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005031138,"threshold_uncertainty_score":0.9958773,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008194344724826242,"score_gpt":0.1963296701225692,"score_spread":0.188135325397743,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}