{"id":"W2059448240","doi":"10.1021/om020355m","title":"Double C−H Activation on Osmium and Ruthenium Centers:  Carbene vs Olefin Products","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":120,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"","keywords":"Chemistry; Osmium; Ruthenium; Carbene; Dehydrogenation; Olefin fiber; Medicinal chemistry; Pentane; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007623636,0.000172538,0.0001806852,0.0001676544,0.00009834965,0.00006652677,0.0001426495,0.00009970715,0.002435974],"category_scores_gemma":[0.00007790029,0.0001634687,0.00004912981,0.0006693511,0.00003830504,0.0001464607,0.00005115829,0.0001435456,0.0002292791],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008513911,"about_ca_system_score_gemma":0.00001112988,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000019324,"about_ca_topic_score_gemma":0.000002038695,"domain_scores_codex":[0.9989259,0.000009243633,0.0001983216,0.0003682287,0.0002835001,0.0002147586],"domain_scores_gemma":[0.9993221,0.00002956168,0.0001063635,0.0003716384,0.00007188116,0.00009849718],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003175258,0.002264096,0.005201559,0.0005778438,0.0008256506,0.00002270879,0.003909966,0.0001175222,0.9070904,0.005778689,0.007650443,0.0662436],"study_design_scores_gemma":[0.001165494,0.00003312088,0.0002815787,0.00001746085,0.0000652993,0.000006826976,0.0001582374,0.0005195176,0.9187559,0.00003414127,0.07866348,0.0002989639],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9358007,0.0001993171,0.00006971767,0.00196036,0.000083666,0.00008935275,0.00001607736,0.0001290663,0.06165173],"genre_scores_gemma":[0.9852857,0.000128449,0.00009246168,0.0002364235,0.0001692978,0.00001117142,0.00009493261,0.00003262041,0.01394892],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07101303,"threshold_uncertainty_score":0.9984759,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02135028726563758,"score_gpt":0.2081257077010641,"score_spread":0.1867754204354265,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}