{"id":"W2059514109","doi":"10.1021/jp051400h","title":"Spontaneous Formation of Core/Shell Bimetallic Nanoparticles:  A Calorimetric Study","year":2005,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"thermodynamics and calorimetric analyses","field":"Chemistry","cited_by":79,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Ministry of Education, Culture, Sports, Science and Technology","keywords":"Exothermic reaction; Bimetallic strip; Nanoparticle; Isothermal titration calorimetry; Enthalpy; Exothermic process; Materials science; Noble metal; Endothermic process; Dispersion (optics); Isothermal process; Calorimetry; Chemical engineering; Metal; Adsorption; Chemistry; Physical chemistry; Nanotechnology; Thermodynamics; Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003088585,0.0002528336,0.0002291057,0.000219544,0.0001900901,0.0001704565,0.0002989042,0.0002504892,0.0008185543],"category_scores_gemma":[0.0005754075,0.0001660451,0.0001826999,0.0001256244,0.0004400499,0.0002841352,0.0001868433,0.0005972915,0.0001672692],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003651941,"about_ca_system_score_gemma":0.0001077326,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003820454,"about_ca_topic_score_gemma":0.0004215219,"domain_scores_codex":[0.9997955,0.00003646503,0.000009658513,0.00005235363,0.00008201401,0.00002401849],"domain_scores_gemma":[0.9997479,0.000105139,0.00003856695,0.00003555496,0.00005539432,0.00001728107],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006082916,0.00002910746,0.0006068925,0.00004936277,0.00001304529,0.00004192737,0.00005288463,0.0005551321,0.9959847,0.0004112213,0.00004151058,0.002153451],"study_design_scores_gemma":[0.000002752539,0.0000395988,0.0008439574,0.000001137656,0.000003626296,0.0000354673,0.000005344431,0.003157227,0.9956563,0.0000364335,0.0002147772,0.000003411958],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905748,0.0003698534,0.008082075,0.00004852601,0.00001415566,0.00002235905,0.0001073041,0.00008109916,0.0006998713],"genre_scores_gemma":[0.9966433,0.000113768,0.002661593,0.00001359133,0.000006413109,0.00002039783,0.00009092305,0.00001632047,0.0004336977],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008185543,"threshold_uncertainty_score":0.002738297,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01702664469079664,"score_gpt":0.2573375775555847,"score_spread":0.2403109328647881,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}