{"id":"W2059559496","doi":"10.1016/j.jpba.2005.04.041","title":"Development of a rapid and sensitive LC–ESI/MS/MS assay for the quantification of propofol using a simple off-line dansyl chloride derivatization reaction to enhance signal intensity","year":2005,"lang":"en","type":"article","venue":"Journal of Pharmaceutical and Biomedical Analysis","topic":"Pesticide Residue Analysis and Safety","field":"Agricultural and Biological Sciences","cited_by":80,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Derivatization; Chromatography; Dansyl chloride; Chloride; Mass spectrometry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001283688,0.001411526,0.0008708776,0.0008428142,0.0004477124,0.0005681997,0.001040579,0.001489328,0.001330215],"category_scores_gemma":[0.001348482,0.001099671,0.0006266026,0.0002610656,0.0006696302,0.0008777592,0.0008097176,0.001632703,0.001302721],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006329975,"about_ca_system_score_gemma":0.00157594,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008581361,"about_ca_topic_score_gemma":0.002401669,"domain_scores_codex":[0.9988617,0.0001568663,0.00008713902,0.0002831871,0.0005391915,0.00007192505],"domain_scores_gemma":[0.9990446,0.0003226428,0.0001348384,0.00006458798,0.0003070138,0.0001262971],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008173837,0.00005284099,0.0002441402,0.00006146878,0.00001586176,0.00002995364,0.00001652647,0.00006602901,0.9916641,0.00009558646,0.0001002725,0.007571625],"study_design_scores_gemma":[0.00004540148,0.0005869225,0.002025096,0.0000117988,0.00003605307,0.0005922252,0.000009366829,0.003285211,0.9909081,0.0001125612,0.002357208,0.00003013809],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.3101864,0.005401346,0.6728498,0.0008094627,0.0006743108,0.001690834,0.001340817,0.002943982,0.004103095],"genre_scores_gemma":[0.4529955,0.002717993,0.5297556,0.001161216,0.0002091226,0.001351531,0.002170107,0.0001843966,0.009454596],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.001489328,"threshold_uncertainty_score":0.006788909,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05478828833965486,"score_gpt":0.3437520520035123,"score_spread":0.2889637636638575,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}