{"id":"W2059787490","doi":"10.1039/b406408a","title":"Evaluation of the simultaneous use of standard additions and internal standards calibration techniques for inductively coupled plasma mass spectrometry","year":2004,"lang":"en","type":"article","venue":"Journal of Analytical Atomic Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Internal standard; Calibration; Standard addition; Inductively coupled plasma mass spectrometry; Analytical Chemistry (journal); Chemistry; Inductively coupled plasma; Thallium; Mass spectrometry; Standard solution; Matrix (chemical analysis); Yttrium; Molybdenum; Cobalt; Chromatography; Plasma; Detection limit; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001530326,0.0002343832,0.0006303379,0.0005391017,0.0001040081,0.0000649423,0.0003576613,0.0002023165,0.0009925783],"category_scores_gemma":[0.002423629,0.0001775296,0.0003692427,0.0008807657,0.0003127974,0.0002792934,0.00007001273,0.0005062576,1.544704e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001293238,"about_ca_system_score_gemma":0.0007566464,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002802449,"about_ca_topic_score_gemma":0.000008883868,"domain_scores_codex":[0.9966376,0.0000597541,0.001117809,0.0002606247,0.001664284,0.0002598605],"domain_scores_gemma":[0.9960085,0.000511815,0.001180115,0.0003564997,0.001810231,0.0001328117],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001074823,0.0008063597,0.00217471,0.0003220201,0.001345257,0.00001077525,0.0001339596,0.0009555462,0.9179448,0.07074799,0.0009115342,0.003572231],"study_design_scores_gemma":[0.002374152,0.0009028576,0.0007484881,0.0003925393,0.001264822,0.0002202577,0.0002431937,0.03251655,0.8657383,0.09465703,0.0006504746,0.0002912725],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8701568,0.000109253,0.1269469,0.0005393839,0.00005167632,0.0003569321,0.0008811282,0.0000334585,0.0009243985],"genre_scores_gemma":[0.9521199,0.0001125355,0.04746597,0.00001638279,0.0001827173,0.00001482959,0.00001039149,0.00002958883,0.00004764143],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08196311,"threshold_uncertainty_score":0.9999207,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02387362000719901,"score_gpt":0.3077772010991491,"score_spread":0.2839035810919501,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}