{"id":"W2059819035","doi":"10.1021/jp010076x","title":"Spectral Properties of Fluorophores Combining the Boronic Acid Group with Electron Donor or Withdrawing Groups. Implication in the Development of Fluorescence Probes for Saccharides","year":2001,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":174,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Center for Research Resources; Natural Sciences and Engineering Research Council of Canada","keywords":"Boronic acid; Chemistry; Fluorescence; Photochemistry; Suzuki reaction; Photoinduced electron transfer; Polar effect; Electron transfer; Organic chemistry; Aryl","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004151804,0.0004682799,0.000163883,0.0002852483,0.0001498828,0.0002186472,0.000226339,0.0005563537,0.001734044],"category_scores_gemma":[0.0004298249,0.0001571087,0.0002376844,0.0001860641,0.0002993676,0.0003389303,0.0001418618,0.0005133002,0.0003286018],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003100829,"about_ca_system_score_gemma":0.0001082267,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004593523,"about_ca_topic_score_gemma":0.0003081993,"domain_scores_codex":[0.9998567,0.00003709499,0.000006566596,0.00002504521,0.00003518822,0.00003946614],"domain_scores_gemma":[0.9996938,0.0001332848,0.00006214073,0.00001538411,0.00005116678,0.00004443027],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004873937,0.000005174188,0.00005914862,0.0000269349,0.000002003623,0.00001230179,0.00001019752,0.00006262282,0.9990861,0.00005416902,0.000007646947,0.0006249416],"study_design_scores_gemma":[0.000002976955,0.00008046994,0.0006119133,0.000002836109,0.000004501047,0.00003901889,0.0000084299,0.0003067715,0.9987189,0.00001870815,0.0002027083,0.000002790109],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898672,0.001215884,0.006671104,0.0001137433,0.00001306159,0.00002106624,0.0001527995,0.00007714152,0.001868016],"genre_scores_gemma":[0.9928778,0.0007809684,0.004898549,0.00005618834,0.000006770936,0.00003437024,0.0001965266,0.00001484833,0.001133953],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001734044,"threshold_uncertainty_score":0.005800962,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01896261458671629,"score_gpt":0.2491486490315416,"score_spread":0.2301860344448253,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}