{"id":"W2060292741","doi":"10.1016/j.inoche.2007.09.036","title":"Microwave-assisted synthesis of [Os2Cl3(PEt2Ph)6]Cl, featuring the first reported X-ray crystal structure","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry Communications","topic":"Microwave-Assisted Synthesis and Applications","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of New Brunswick","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Osmium; Microwave; Characterization (materials science); Crystal structure; X-ray; Single crystal; Chemistry; Crystallography; Crystal (programming language); Spectroscopy; Materials science; Nanotechnology; Ruthenium; Organic chemistry; Optics; Catalysis; Computer science; Physics; Telecommunications","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00049673,0.000417644,0.0004750834,0.00005291381,0.001052099,0.00009795081,0.002846496,0.0004123317,0.001756198],"category_scores_gemma":[0.0007287318,0.0003672761,0.000269583,0.0007868818,0.0006322596,0.00009472698,0.0007525758,0.0008617976,0.00001617604],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002664002,"about_ca_system_score_gemma":0.0002229501,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001077899,"about_ca_topic_score_gemma":0.0004597171,"domain_scores_codex":[0.9972833,0.00003862652,0.001247874,0.0005292405,0.0003842848,0.0005166781],"domain_scores_gemma":[0.9913814,0.00139004,0.000957566,0.005704269,0.000397562,0.0001691401],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001726314,0.0002789572,0.0009485599,0.0002326404,0.0002377712,0.000003344225,0.0003520492,0.000002882107,0.994205,0.0001239808,0.001031492,0.002566064],"study_design_scores_gemma":[0.0002595994,0.000002596124,0.004219413,0.000209383,0.0002474989,0.0001870001,0.001334734,0.00004187518,0.9571263,0.00008377569,0.03590742,0.0003803621],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9343797,0.00151897,0.000402676,0.00263694,0.00004887434,0.0002705707,0.0003992937,0.0002926123,0.06005036],"genre_scores_gemma":[0.9953167,0.0001791261,0.002972718,0.00006386942,0.0001237906,0.00006179169,0.0002177773,0.0000822195,0.0009820294],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06093697,"threshold_uncertainty_score":0.9998779,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01886164675889521,"score_gpt":0.2449137026761026,"score_spread":0.2260520559172074,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}