{"id":"W2060336035","doi":"10.1016/j.tet.2011.07.026","title":"Directing/protecting groups mediate highly regioselective glycosylation of monoprotected acceptors","year":2011,"lang":"en","type":"article","venue":"Tetrahedron","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University","funders":"","keywords":"Regioselectivity; Chemistry; Glycosylation; Monosaccharide; Protecting group; Stereoselectivity; Surface modification; Combinatorial chemistry; Stereochemistry; Organic chemistry; Biochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006250353,0.0007851563,0.0002704575,0.0003713493,0.0002667814,0.0004502617,0.0006830368,0.0004548249,0.002085051],"category_scores_gemma":[0.0003459352,0.0002777393,0.0002895225,0.0003106644,0.0003433836,0.0004602081,0.0005044165,0.001051088,0.00122523],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004532972,"about_ca_system_score_gemma":0.0003290102,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004556491,"about_ca_topic_score_gemma":0.0009735354,"domain_scores_codex":[0.9997644,0.00004386062,0.00001921505,0.00004148397,0.00003934634,0.00009175909],"domain_scores_gemma":[0.9998413,0.00004169365,0.00003965662,0.00003426403,0.00001512219,0.00002787309],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003803808,0.00009058631,0.00019672,0.00009895724,0.00001636435,0.0005596363,0.0001308391,0.0008445172,0.9808571,0.00730241,0.0005588581,0.008963651],"study_design_scores_gemma":[0.00002215809,0.0001196182,0.0002140145,0.000006545072,0.00001243837,0.0001517903,0.00001237941,0.0005058033,0.9959096,0.0003578839,0.002680927,0.00000679815],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9333515,0.001450612,0.04225726,0.0003636093,0.0001621205,0.0001398644,0.0006395801,0.0005990234,0.0210366],"genre_scores_gemma":[0.983282,0.001331739,0.009802829,0.0001372453,0.00004955846,0.00004151376,0.0005191126,0.0001144362,0.004721527],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002085051,"threshold_uncertainty_score":0.006975234,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03087097500350337,"score_gpt":0.2105659829959201,"score_spread":0.1796950079924167,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}