{"id":"W2060388753","doi":"10.1021/ja065249g","title":"Carbene vs Olefin Products of C−H Activation on Ruthenium via Competing α- and β-H Elimination","year":2006,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University; University of Toronto","funders":"","keywords":"Chemistry; Carbene; Pincer movement; Olefin fiber; Ruthenium; Pincer ligand; Ligand (biochemistry); Medicinal chemistry; Cyclohexane; Nuclear magnetic resonance spectroscopy; Photochemistry; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001809739,0.0001014183,0.0002889848,0.00001487574,0.00005285068,0.00001379873,0.0001874512,0.00003207431,0.0000887554],"category_scores_gemma":[0.0001204753,0.00006986429,0.0002346692,0.0002229173,0.0001878014,0.00004614596,0.00005917947,0.00019161,4.220472e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001009503,"about_ca_system_score_gemma":0.00002652566,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004571307,"about_ca_topic_score_gemma":2.767618e-7,"domain_scores_codex":[0.9990949,0.00001925585,0.0003431609,0.0001179085,0.0003142156,0.0001105679],"domain_scores_gemma":[0.9985888,0.0001554617,0.0009297775,0.0001711465,0.0001264342,0.0000283511],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003973466,0.0001089727,0.0008349277,0.00003741151,0.0000579254,9.913982e-8,0.0001373986,0.00002279363,0.9936682,0.00002456101,0.0002071563,0.004860816],"study_design_scores_gemma":[0.0001767007,0.00001965472,0.006718287,0.00005192676,0.00007532354,0.000008979569,0.0003387631,0.0002171536,0.9916321,0.0001082621,0.0005756416,0.00007722268],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968985,0.00004067598,0.00006499577,0.002307215,0.00001502226,0.00001934622,0.000003974919,0.000005815347,0.0006445029],"genre_scores_gemma":[0.9985376,0.00001407439,0.0009857179,0.00007902909,0.000271143,7.63026e-7,0.000002971041,0.00001154608,0.00009714569],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005883359,"threshold_uncertainty_score":0.2848983,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006658085094632455,"score_gpt":0.2068555571666276,"score_spread":0.2001974720719951,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}