{"id":"W2060474839","doi":"10.1021/jp049785b","title":"Methyl Pyruvate on Ni(111):  Coverage-Dependent Thermal Chemistry","year":2004,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Decarbonylation; Chemistry; Bond cleavage; Decomposition; Platinum; Hydrogen; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002399077,0.00027173,0.0003375195,0.000008237097,0.00007743478,0.00003412566,0.0005614272,0.0001015714,0.0002058105],"category_scores_gemma":[0.00004937262,0.0001916304,0.0002680987,0.0001488224,0.00009022035,0.0001055885,0.00004642202,0.0007971469,0.00004387659],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001802887,"about_ca_system_score_gemma":0.00004819345,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002583238,"about_ca_topic_score_gemma":7.00557e-8,"domain_scores_codex":[0.9987646,0.00001438831,0.0003237067,0.0001249942,0.0004836078,0.000288746],"domain_scores_gemma":[0.9990938,0.0001215516,0.0001549184,0.0003926801,0.00007574836,0.0001613041],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007414748,0.000105331,0.000003360595,0.00008401649,0.0001596106,0.00002612181,0.0002381944,0.1907108,0.8079715,0.000001188056,0.00009280559,0.0005329479],"study_design_scores_gemma":[0.0007014358,0.00003541126,0.00002735673,0.00006585957,0.0001304213,0.00005629675,0.0001497552,0.0001937047,0.9978458,0.0003920148,0.0001892774,0.0002126945],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9868143,0.0001824443,0.0001095119,0.0001524397,0.00006220177,0.00003086833,0.00001231579,0.00006215134,0.01257382],"genre_scores_gemma":[0.9986245,0.00005018082,0.00001337654,0.00003521335,0.000812211,0.000002164442,0.000005360052,0.00003861301,0.0004183867],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1905171,"threshold_uncertainty_score":0.781446,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005438438120910987,"score_gpt":0.2031197322563486,"score_spread":0.1976812941354376,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}