{"id":"W2060550258","doi":"10.1002/app.24216","title":"Photoregulated complexation, redox behavior, and photoluminescence of a supramolecular polymer solution","year":2006,"lang":"en","type":"article","venue":"Journal of Applied Polymer Science","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Photoisomerization; Redox; Photochemistry; Supramolecular chemistry; Moiety; Tetraphenylporphyrin; Photoluminescence; Polymer; Supramolecular polymers; Polymer chemistry; Electrochemistry; Chemistry; Cyclic voltammetry; Materials science; Physical chemistry; Inorganic chemistry; Electrode; Molecule; Organic chemistry; Porphyrin; Catalysis; Isomerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000164267,0.0002847706,0.0002221911,0.0001771784,0.0001400544,0.0003570773,0.0002544929,0.0003350989,0.001166755],"category_scores_gemma":[0.0003304323,0.0001389699,0.0001746695,0.0001296496,0.0003115637,0.0003046627,0.0002094543,0.0006268931,0.0002200625],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003093398,"about_ca_system_score_gemma":0.0001139734,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002089745,"about_ca_topic_score_gemma":0.0002159488,"domain_scores_codex":[0.9998456,0.00002392919,0.000007633554,0.00005239807,0.00004715366,0.00002324554],"domain_scores_gemma":[0.9998478,0.00004315689,0.00004121123,0.00001889727,0.00002150879,0.00002742377],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001146967,0.000005930473,0.00002520818,0.00001121654,0.000002087275,0.00001398538,0.00001136079,0.000017444,0.9992369,0.00004358578,0.000009529697,0.000611204],"study_design_scores_gemma":[0.000003190418,0.00004885386,0.0003107828,8.970915e-7,0.000003076357,0.00004293563,0.000004618248,0.0002038495,0.9991598,0.00001760526,0.0002027612,0.000001650249],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902356,0.000915162,0.007085673,0.0001335594,0.00002835957,0.00002422408,0.00007954535,0.0001373148,0.001360424],"genre_scores_gemma":[0.9964443,0.0001869857,0.002306365,0.00005122396,0.000008053831,0.00001577394,0.00006003659,0.00001568364,0.0009116131],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001166755,"threshold_uncertainty_score":0.00390321,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005337978792353958,"score_gpt":0.2119246360692571,"score_spread":0.2065866572769031,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}