{"id":"W2060566628","doi":"10.1002/chin.201124275","title":"ChemInform Abstract: The Role of Preassociation in Broensted Acid Catalyzed Decarboxylation and Related Processes","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Decarboxylation; Catalysis; Organic chemistry; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009994964,0.001020531,0.0005960006,0.001405592,0.0006360642,0.001566261,0.001120408,0.00140093,0.0199792],"category_scores_gemma":[0.001086169,0.0003675461,0.0003477932,0.00207421,0.0008952739,0.002322223,0.001022461,0.00273404,0.01623882],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001634589,"about_ca_system_score_gemma":0.001559648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001429594,"about_ca_topic_score_gemma":0.002185086,"domain_scores_codex":[0.9996603,0.00003338093,0.00002189387,0.00007436555,0.0001656546,0.00004441061],"domain_scores_gemma":[0.9993145,0.0001884255,0.00006000665,0.0000409046,0.0003332554,0.00006283739],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0002914271,0.00008007653,0.0002137127,0.01313771,0.0001072258,0.0003428363,0.00007900282,0.0009314615,0.01452935,0.06653123,0.3903024,0.5134536],"study_design_scores_gemma":[0.00001384066,0.00005202104,0.0002280407,0.0004715018,0.00003175407,0.0002902561,0.00001821789,0.0001262559,0.007506234,0.003009362,0.9882355,0.00001701178],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"other","genre_scores_codex":[0.001539621,0.9029053,0.002975768,0.005185002,0.01565923,0.00005022439,0.0004163913,0.0001557559,0.07111264],"genre_scores_gemma":[0.01498538,0.9305365,0.001626048,0.003292475,0.00566362,0.00004216337,0.0006713479,0.00004684495,0.04313566],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.0199792,"threshold_uncertainty_score":0.06683713,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009064272605028522,"score_gpt":0.1956396278031244,"score_spread":0.1865753551980959,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}