{"id":"W2060588909","doi":"10.1021/jp0526602","title":"Gas-Phase Reactions of Carbon Dioxide with Atomic Transition-Metal and Main-Group Cations:  Room-Temperature Kinetics and Periodicities in Reactivity","year":2005,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":134,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Ion; Atom (system on chip); Analytical Chemistry (journal); Metal; Reactivity (psychology); Inorganic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002011259,0.0004100902,0.0001886691,0.000226787,0.0002631357,0.0002382346,0.0003712166,0.0004080602,0.001042295],"category_scores_gemma":[0.0003648035,0.000154152,0.0001854735,0.0001995199,0.0004085472,0.0002418583,0.0001546346,0.0002173761,0.000198205],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004909856,"about_ca_system_score_gemma":0.0002573657,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002435635,"about_ca_topic_score_gemma":0.003524262,"domain_scores_codex":[0.9998025,0.0000202778,0.000006049721,0.00006083437,0.0000654236,0.0000448458],"domain_scores_gemma":[0.9998131,0.00007110889,0.00002429761,0.00001708214,0.00005023781,0.00002411466],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003715192,0.00001683041,0.004223572,0.00008574789,0.00002075238,0.00007924138,0.00005809334,0.0004746456,0.9917312,0.0001049577,0.00008256524,0.002750796],"study_design_scores_gemma":[0.000006680089,0.0001928605,0.007426967,0.000001918064,0.000007207245,0.00009672236,0.0000274283,0.001185761,0.9901307,0.00003089075,0.0008854163,0.000007442085],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964868,0.000880515,0.0009015049,0.00003164025,0.000009540364,0.00001792635,0.0002127067,0.00004439329,0.001414992],"genre_scores_gemma":[0.9982156,0.0002212324,0.0005832851,0.000009358741,0.000004774938,0.0000120674,0.0002759804,0.00001316656,0.0006646229],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002435635,"threshold_uncertainty_score":0.004842877,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004620929685724527,"score_gpt":0.2318679611934712,"score_spread":0.2272470315077467,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}