{"id":"W2060646523","doi":"10.1002/hlca.200290023","title":"Synthesis of <i>α</i>‐Nitro‐<i>α</i>‐diazocarbonyl Derivatives and Their Applications in the Cyclopropanation of Alkenes and in OH Insertion Reactions","year":2002,"lang":"en","type":"article","venue":"Helvetica Chimica Acta","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":72,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Cyclopropanation; Diazo; Chemistry; Nitro; Carbene; Reagent; Azide; Trifluoromethyl; Sulfonyl; Rhodium; Medicinal chemistry; Steric effects; Catalysis; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000163543,0.0001741083,0.0002693128,0.0002011182,0.00006504544,0.00001720944,0.0001602952,0.0001191065,0.00005373938],"category_scores_gemma":[0.0002037177,0.0001350944,0.00004450082,0.0003640936,0.0001811532,0.0001375749,0.00004642328,0.0002090457,8.029719e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004125043,"about_ca_system_score_gemma":0.00001539067,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008714249,"about_ca_topic_score_gemma":0.0001128325,"domain_scores_codex":[0.9988685,0.00007650896,0.0004459476,0.0002790786,0.0001639849,0.0001659447],"domain_scores_gemma":[0.9986821,0.0006465407,0.0002255385,0.0003482218,0.00005720309,0.00004039229],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002214712,0.0002360088,0.002765137,0.0002248309,0.00001328281,3.758979e-7,0.002084075,0.000001414357,0.9914382,0.0008937739,0.000004119322,0.002316636],"study_design_scores_gemma":[0.0003947718,0.00002617486,0.02457625,0.0001884661,0.00003994224,0.00003003867,0.00851378,0.0006329691,0.9631559,0.001271561,0.00097409,0.0001960731],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9932483,0.000227026,0.00003438773,0.0007216752,0.000009527917,0.0002571171,0.00002516588,0.00002500456,0.005451802],"genre_scores_gemma":[0.9980181,0.001386324,0.0003261682,0.00002292333,0.00002111496,0.0001786454,0.00001106537,0.00001969331,0.00001596317],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02828231,"threshold_uncertainty_score":0.5508991,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01389541706945068,"score_gpt":0.2159501795957625,"score_spread":0.2020547625263118,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}