{"id":"W2060779858","doi":"10.1021/om701236k","title":"Different Modes of Reactivity of Cp*W(NO)(alkyl)(η<sup>3</sup>-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Inorganic and Organometallic Chemistry","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Alkyl; Reactivity (psychology); Medicinal chemistry; Cyclic amines; Allyl chloride; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002396643,0.0003820951,0.0002053068,0.0001270779,0.0001091478,0.0004417516,0.0004410309,0.0003232201,0.001521437],"category_scores_gemma":[0.0004006206,0.0001940306,0.0001163442,0.00009919311,0.0002951844,0.000260652,0.0002222875,0.0003617033,0.0003290761],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003275168,"about_ca_system_score_gemma":0.0001329293,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005935036,"about_ca_topic_score_gemma":0.0008355674,"domain_scores_codex":[0.999851,0.00002783278,0.00001071875,0.00003113715,0.00003507344,0.00004429518],"domain_scores_gemma":[0.999816,0.00006192375,0.00005251148,0.00001776151,0.00002129413,0.00003040905],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003942273,0.00002600178,0.0002538932,0.000058538,0.0000168722,0.000056785,0.00006825822,0.0003930232,0.9968256,0.0002586042,0.0000623933,0.001585806],"study_design_scores_gemma":[0.00001314274,0.0001055416,0.0003295539,0.000001623157,0.000006729224,0.0000341791,0.000008474082,0.0006666635,0.9984994,0.00001842386,0.0003119404,0.000004286445],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973561,0.0002339114,0.0007507273,0.00002061437,0.000005997384,0.00001323516,0.00006349297,0.00005009547,0.001506057],"genre_scores_gemma":[0.9985535,0.0001075287,0.0004512895,0.00001187685,0.00000195679,0.0000110843,0.00007727459,0.00001961788,0.0007659672],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001521437,"threshold_uncertainty_score":0.0050897,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009785248416988161,"score_gpt":0.1921626682807626,"score_spread":0.1823774198637745,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}