{"id":"W2060812952","doi":"10.1139/v08-133","title":"Mechanistic investigations of bipyrimidine-promoted palladium-catalyzed allylic acetoxylation of olefins","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Allylic rearrangement; Chemistry; Cyclohexene; Catalysis; Medicinal chemistry; Olefin fiber; Dimer; Adduct; Palladium; Pyridine; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003046432,0.0001853959,0.000416232,0.0001780471,0.0001081301,0.00001178224,0.0003518225,0.000213676,0.003295637],"category_scores_gemma":[0.001816525,0.000206361,0.000196721,0.0004379775,0.0003248955,0.0001163703,0.0000182771,0.0002727624,0.00000374445],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002608846,"about_ca_system_score_gemma":0.003387793,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000773538,"about_ca_topic_score_gemma":0.000446137,"domain_scores_codex":[0.9982201,0.00002296905,0.0009692677,0.000170696,0.0003839941,0.0002329247],"domain_scores_gemma":[0.9970439,0.0001634949,0.0009934223,0.0003743153,0.0008209018,0.0006039782],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002035738,0.00003366743,0.002808613,0.0003102827,0.000119423,0.00003727479,0.0003736972,0.00075961,0.994274,0.000149895,0.0009744473,0.0001387067],"study_design_scores_gemma":[0.0007684407,0.00001389026,0.0008431793,0.0001988152,0.0001035638,0.0006015821,0.0001637062,0.0003604935,0.9940223,0.001173125,0.001564814,0.0001861451],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9894428,0.0003535315,0.004068671,0.0002333475,0.0001366545,0.00004790308,0.0001821225,0.00001291824,0.005522047],"genre_scores_gemma":[0.9949163,0.00002934638,0.003646323,0.00002989799,0.0001972869,0.000002431485,0.0001792395,0.00003189619,0.0009673043],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005473469,"threshold_uncertainty_score":0.9976155,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03524752059569741,"score_gpt":0.244618365916078,"score_spread":0.2093708453203806,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}