{"id":"W2061059347","doi":"10.1021/ja9029945","title":"2,3-Anhydrosugars in Glycoside Bond Synthesis: Mechanism of 2-Deoxy-2-thioaryl Glycoside Formation","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Glycomics Centre; University of Alberta","funders":"","keywords":"Chemistry; Glycoside; Stereochemistry; Mechanism (biology); Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004140315,0.0002530187,0.0007129745,0.00003041297,0.00006311909,0.00002746084,0.0007398706,0.0001593418,0.00007672809],"category_scores_gemma":[0.0004837048,0.0001899939,0.0009881933,0.0004260556,0.0002692653,0.0002054765,0.00008859206,0.0006600242,0.000001711805],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003747936,"about_ca_system_score_gemma":0.00009455101,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003199137,"about_ca_topic_score_gemma":0.000001246577,"domain_scores_codex":[0.997839,0.0000335041,0.0009863658,0.0001959181,0.000588802,0.000356431],"domain_scores_gemma":[0.9974089,0.0003748771,0.001547515,0.0004149841,0.0001194156,0.0001342898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001455709,0.0001748364,0.0001557241,0.00006449583,0.0000633738,0.000007467296,0.0004696716,0.00002820157,0.9955587,0.00004496184,0.001771146,0.001515842],"study_design_scores_gemma":[0.0003788484,0.00002682014,0.0001029299,0.0002997453,0.0001097258,0.0001345605,0.001347757,0.0003940591,0.9948563,0.001953564,0.0001934391,0.0002022283],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958194,0.0001222888,0.00006812572,0.00207503,0.00004130532,0.00004283009,0.00001507039,0.00001724635,0.001798688],"genre_scores_gemma":[0.9975575,0.0001892059,0.001506062,0.0005034016,0.0001786241,0.000004105477,0.000001466985,0.00001938629,0.00004020297],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001908602,"threshold_uncertainty_score":0.7747726,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008775933352489102,"score_gpt":0.223915133215584,"score_spread":0.2151391998630949,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}