{"id":"W2061375988","doi":"10.1021/ol035546f","title":"Versatile Route to <i>centro</i>-Substituted Triquinacene Derivatives:  Synthesis of 10-Phenyltriquinacene","year":2003,"lang":"en","type":"article","venue":"Organic Letters","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Trimethylsilyl; Moiety; Intramolecular force; Enone; Ketene; Acetal; Magnesium bromide; Conjugate; Enol; Bromide; Aldol reaction; Enol ether; Bicyclic molecule; Pyridinium; Medicinal chemistry; Vinyl ether; Substituent; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001169527,0.0003485978,0.0001868827,0.0001557535,0.0001405761,0.0002266845,0.0005214727,0.0002223693,0.003230338],"category_scores_gemma":[0.000103511,0.0001608366,0.0001387111,0.0001524385,0.0001829209,0.0002006082,0.0002866982,0.0004755235,0.001216442],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002813847,"about_ca_system_score_gemma":0.0002701604,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004548385,"about_ca_topic_score_gemma":0.001175377,"domain_scores_codex":[0.9999222,0.00001000694,0.000006885788,0.00001948133,0.00002047078,0.00002098883],"domain_scores_gemma":[0.9999347,0.000008402351,0.00001790559,0.00001003908,0.00001098655,0.00001803512],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004225663,0.00002359574,0.00005051951,0.00007667874,0.000004884875,0.0001736811,0.00003392392,0.0002330465,0.9947737,0.0004611606,0.0001725808,0.003954099],"study_design_scores_gemma":[0.00002816143,0.0002782128,0.0003739026,0.000007361098,0.000007621202,0.0005546569,0.0000126057,0.0004063642,0.9893607,0.00007960288,0.008881733,0.000008869716],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9006381,0.005086645,0.05082365,0.0003805862,0.0002035597,0.0003176707,0.00102262,0.000866033,0.04066117],"genre_scores_gemma":[0.9662964,0.002883368,0.02033021,0.0001516067,0.00002178271,0.00007816296,0.0005480905,0.00009184183,0.009598533],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003230338,"threshold_uncertainty_score":0.01080656,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00938747382136007,"score_gpt":0.2102663302487543,"score_spread":0.2008788564273942,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}