{"id":"W2061447113","doi":"10.1002/macp.201100021","title":"Termination Kinetics of 1‐Vinylpyrrolidin‐2‐one Radical Polymerization in Aqueous Solution","year":2011,"lang":"en","type":"article","venue":"Macromolecular Chemistry and Physics","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Monomer; Microsecond; Aqueous solution; Polymerization; Kinetics; Bar (unit); Diffusion; Yield (engineering); Analytical Chemistry (journal); Radical polymerization; Polymer chemistry; Photochemistry; Polymer; Physical chemistry; Thermodynamics; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004182186,0.0001776425,0.0002231807,0.00000657904,0.00004107442,0.000008227946,0.0001195774,0.0001472723,0.0001249198],"category_scores_gemma":[0.00002057173,0.0002115885,0.00005902931,0.0001326267,0.0001697001,0.00005255079,0.00003982879,0.0001789727,6.964623e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002904564,"about_ca_system_score_gemma":0.00001953331,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003194582,"about_ca_topic_score_gemma":0.000001405342,"domain_scores_codex":[0.9990723,0.00001091695,0.0002632271,0.0002611305,0.0001553531,0.000237037],"domain_scores_gemma":[0.9996052,0.00001477366,0.00008413047,0.0001972056,0.00003845351,0.00006017221],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006913241,0.0003386738,0.0004395256,0.0005027486,0.00003528547,0.00001401688,0.0005151925,0.000001632608,0.9907504,0.00008251227,0.000003072356,0.007247855],"study_design_scores_gemma":[0.0005318222,0.00002427638,0.0002251805,0.00008237997,0.00004339548,0.00001809846,0.00004278552,0.0003734752,0.9970542,0.001358968,0.00004351148,0.0002019294],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9765018,0.0005288524,0.005628924,0.00002501576,0.00001180668,0.00005432107,0.00002563925,0.00003415137,0.01718949],"genre_scores_gemma":[0.9992362,0.000134355,0.0003349773,0.00001369559,0.00005824151,0.00002054752,0.00008984712,0.00001710252,0.00009506866],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02273436,"threshold_uncertainty_score":0.8628329,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0119004457524722,"score_gpt":0.2069972214901757,"score_spread":0.1950967757377035,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}