{"id":"W2061574139","doi":"10.1002/cctc.201200679","title":"In‐Situ Spectroscopic Detection of Active Surface Species in Asymmetric Heterogeneous Catalysis","year":2013,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Cinchonidine; In situ; Catalysis; Chemistry; Heterogeneous catalysis; Diastereomer; Enantioselective synthesis; Asymmetric hydrogenation; Photochemistry; Spectroscopy; Stereochemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006416214,0.0001850834,0.0003276536,0.0001596385,0.00001354077,0.00001586409,0.0001705201,0.0001289504,0.0001732279],"category_scores_gemma":[0.00003739067,0.0002060218,0.0000895639,0.001295301,0.00003977252,0.0002078539,0.0000331982,0.0001979233,0.00009270185],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002781778,"about_ca_system_score_gemma":0.00001158476,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002477209,"about_ca_topic_score_gemma":0.0001429315,"domain_scores_codex":[0.9990469,0.000009128516,0.0002954945,0.0002270378,0.0001423489,0.0002791038],"domain_scores_gemma":[0.9994879,0.0000607597,0.00005044255,0.0003064072,0.0000378387,0.00005667845],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004753199,0.00004731998,0.001847811,0.00008469415,0.00004151556,0.000004381973,0.0004257876,0.002144075,0.9938082,3.386079e-7,0.00003078604,0.001560299],"study_design_scores_gemma":[0.0002557782,0.000008501731,0.009545993,0.00001475814,0.00001620954,0.000003213195,0.0004386599,0.0003696486,0.9890752,0.00004610488,0.0000475194,0.0001783403],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9931394,0.000485126,0.0000585847,0.00002224803,0.0000799148,0.0001157016,0.000002779956,0.000060037,0.006036168],"genre_scores_gemma":[0.9993478,0.00009994988,0.00009797428,0.000005668374,0.00003054756,0.00002511248,0.00001608593,0.00002343841,0.0003534215],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007698182,"threshold_uncertainty_score":0.8401324,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006186828680576142,"score_gpt":0.1919640053277226,"score_spread":0.1857771766471464,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}