{"id":"W2061601782","doi":"10.1021/ma0258915","title":"Exploring the Scope of Possible Microstructures Accessible from Polymerization of Ethylene by Late Transition Metal Single-Site Catalysts. A Theoretical Study","year":2003,"lang":"en","type":"article","venue":"Macromolecules","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Diimine; Polyethylene; Branching (polymer chemistry); Catalysis; Polymerization; Ethylene; Polymer; Materials science; Transition metal; Polymer chemistry; Coordination polymerization; Chemical physics; Chemistry; Photochemistry; Chemical engineering; Organic chemistry; Radical polymerization; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001694657,0.0002219758,0.00040658,0.00006986407,0.0001120006,0.00006085345,0.0003110358,0.00005535403,0.002533855],"category_scores_gemma":[0.00006563056,0.0001663344,0.0001752033,0.0003654673,0.0002506721,0.0001515511,0.00005986695,0.0001098826,0.000003202756],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001943196,"about_ca_system_score_gemma":0.00002713555,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004515307,"about_ca_topic_score_gemma":0.00003573587,"domain_scores_codex":[0.9984942,0.0001301092,0.0004846384,0.0003456112,0.0003340238,0.0002114175],"domain_scores_gemma":[0.9990464,0.0001149196,0.0002191684,0.0005085506,0.00005835732,0.00005262512],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004607155,0.0003542128,0.0003031557,0.00004455354,0.0002595316,0.000003367707,0.00172997,0.00001332069,0.9914766,0.0003650665,0.000002575262,0.005401566],"study_design_scores_gemma":[0.000386492,0.00004587435,0.0008917891,0.00004013938,0.0003412935,0.000002615086,0.001075356,0.00001821121,0.9965395,0.0004437188,0.00004550883,0.0001695394],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951208,0.001758522,0.0004485381,0.00004277184,0.00003789434,0.0001074786,0.0003769828,0.00002719639,0.002079876],"genre_scores_gemma":[0.9993936,0.00006587656,0.0001800184,0.00001529586,0.00002018467,0.00002370918,0.0002190805,0.00003517121,0.00004708425],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005232027,"threshold_uncertainty_score":0.998378,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02245888934936419,"score_gpt":0.2254282718548592,"score_spread":0.202969382505495,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}